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The mean association number: Ultraviolet spectroscopic study of PbCl2−H2O−C2H5OH

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Abstract

The concept of mean asociation number (MAN) has been proposed to describe the association state of an electrolyte. Both the mean spherical approximation (MSA) and the generalized mean spherical approximation (GMSA) are used to calculate the MAN. The theoretical results obtained are compared to the experiment results from an ultraviolet spectroscopic study of PbCl2−H2O−C2H5OH solutions and also to the predictions of the Bjerrum theory as given by Friedman.

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References

  1. R. H. Byrne and D. R. Kester,Marine Chem. 4, 275 (1976).

    Google Scholar 

  2. R. H. Byrne and D. R. Kester,J. Solution Chem. 10, 51 (1981).

    Google Scholar 

  3. R. H. Byrne and D. R. Kester,J. Solution Chem. 7, 373 (1978).

    Google Scholar 

  4. R. H. Byrne, W. Young, and L. Miller,J. Solution Chem. 10, 251 (1981).

    Google Scholar 

  5. H. L. Friedman,J. Solution Chem. 9, 371 (1980).

    Google Scholar 

  6. H. L. Friedman and B. Larsen,J. Pure Appl. Chem. 51, 2147 (1979).

    Google Scholar 

  7. L. Blum,Mol. Phys. 30, 1529 (1975).

    Google Scholar 

  8. L. Blum,Theoretical Chemistry—Advances and Perspectives 5, H. Eyring and D. Henderson, eds., (Academic Press, 1980), p. 1.

  9. J. L. Lebowitz and J. Percus,Phys. Rev. 144, 251 (1966).

    Google Scholar 

  10. J. S. Hoye, J. J. Lebowitz, and G. Stell,J. Chem. Phys. 61, 3253 (1974).

    Google Scholar 

  11. E. Waisman and J. L. Lebowitz,J. Chem. Phys. 56, 3086, 3093 (1972).

    Google Scholar 

  12. F. Hiroike and K. Arakawa,Bull. Chem. Soc. Jpn. 48, 2139 (1975).

    Google Scholar 

  13. G. Stell and S. F. Sun,J. Chem. Phys. 63, 5333 (1975).

    Google Scholar 

  14. L. Onsager,J. Chim. Phys. Numero. Speciale Oct., (1969), discussion.

  15. Huang Zhiqing,Introduce to Electrolyte Solution, (Science Press, Beijing, 1982).

    Google Scholar 

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Wei, D., Lu, J. & Wei, T. The mean association number: Ultraviolet spectroscopic study of PbCl2−H2O−C2H5OH. J Solution Chem 15, 743–748 (1986). https://doi.org/10.1007/BF00646715

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  • DOI: https://doi.org/10.1007/BF00646715

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