Abstract
The enthalpies of crystallization of LiCl and LiCl·H2O from aqueous solutions at 25°C are reported as measured by a calorimetric method and derived from the previously published concentration dependence of the enthalpy of solution data. The results are compared with those obtained from the concentration dependence of activity coefficients and from the temperature dependence of solubilities.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
H. H. Emons, G. Wolf, and L. Kropp,Thermochim. Acta 81, 59 (1984).
V. Vacek and A. König,Thermochim. Acta 70, 225 (1983).
V. Pekárek and V. Vacek,Industrial Crystallization, S. J. Jančic and E. J. de Jong, eds., (North-Holland, Amsterdam, 1982), p. 305.
H. F. Holmes and R. E. Mesmer,J. Phys. Chem. 87, 1242 (1983).
E. Lange and F. Dürr,Z. Physik. Chem. 121, 361 (1926).
V. B. Parker,Natl. Stand. Ref. Data Series NSRDS-NBS 2 (1965).
Gmelins Handbuch der Anorganische Chemie, Syst. No. 20, Lithium, (Verlag Chemie, Weinheim, 1927).
Landolt-Börnstein New Ser. IV/2, Heat of Mixing and Solution, S. Beggerow and K. H. Hellwege, eds., (Springer-Verlag, Berlin, 1976).
V. G. Tsvetkov and L. Ya. Tsvetkov,Zh. Fiz. Khim. VINITI Rep. No. 7683-73 (1973).
Z. Adamcová and S. Beneš,Chem. Prům.27, 606 (1977).
M. Broul, J. Nýylt, and O. Söhnel,Tables of Solubilities of Inorganic Substances in Water, (Academia, Prague, 1979).
F. W. Linke and A. Seidell,Solubilities, of Inorganic and Metal Organic Compounds, (Van Nostrand, New York, 1953).
M. A. Clynne and R. W. Potter,J. Chem. Eng. Data 24, 338 (1979).
W. J. Hamer and Yung-Chi Wu,J. Phys. Chem. Ref. Data 1, 1047 (1972).
R. A. Robinson and R. H. Stokes,Electrolyte Solutions, Butterworths, London, 1959).
I. E. Voznesenskaya, ‘Extended Tables of Activity and Osmotic Coefficients of Aqueous Solutions for 150 Electrolytes at 25°C’ inPhysicochemical Problems of Electrolyte Solutions, G. I. Mikulin, ed., (Khimia, Leningrad, 1968).
A. T. Williamson,Trans. Faraday Soc. 40, 421 (1944).
H. Nakayama,Bull. Fac. Engng., Yokohama Natl. Univ. 19, 29 (1970).
A. N. Kirgintsev and A. V. Lukyanov,Zhur. Neorg. Khim. 12, 2032 (1967).
R. W. Potter and M. A. Clynne,J. Chem. Eng. Data 25, 50 (1980).
D. Blaho, M. Abbrent, and V. Pekárek,Chem. Zvesti 30, 621 (1976).
S. Kolařik, V. Pekárek, and J. Hostomský,Coll. Czech. Chem. Commun. 48, 1632 (1983).
A. Apelblat, R. Weintraub, and A. Tamir,J. Chem. Thermodyn. 16, 935 (1984).
A. Phillipson and G. R. Finlay,Can. J. Chem. 54, 3161 (1976).
V. G. Tsvetkov and I. B. Rabinovich,Russ. J. Phys. Chem. 43, 675 (1969).
S. I. Drakin and S. Yumin,Russ. J. Phys. Chem.,38, 1526 (1964).
I. Wadsö,Science Tools 13, 33 (1966).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wolf, G., Jahn, H., Pekárek, V. et al. Enthalpy of crystallization of lithium chloride from aqueous solution at 25°C. J Solution Chem 15, 269–282 (1986). https://doi.org/10.1007/BF00646695
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00646695