Abstract
Freezing temperatures of dilute aqueous solutions of D-mannitol, myo-inositol, D-mannitol + myo-inositol, D-mannitol + cyclohexanol, and myo-inositol + cyclohexanol have been measured over the concentration range 0.1 to 1.0 mol-kg−1. These data yield pairwise molecular Gibbs energies of interaction which have been corrected to 25°C and treated according to the Savage-Wood additivity principle to give pairwise functional group Gibbs energies of interaction for CH2/CH2, CH2/COOH, and CHOH/CHOH. Anomalous behavior of some systems is discussed in terms of the interactions.
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Spitzer, J.J., Tasker, I.R. & Wood, R.H. Gibbs energies of interaction of the CH2 and CHOH groups from freezing point data for aqueous binary mixtures of D-mannitol,myo-inositol, and cyclohexanol. J Solution Chem 13, 221–232 (1984). https://doi.org/10.1007/BF00646396
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DOI: https://doi.org/10.1007/BF00646396