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Predicted and experimental standard electrode potentials in liquid ammonia at 25°C

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Abstract

Methods are described for the prediction of standard Gibbs free energies of formation of monatomic and polyatomic ions in liquid ammonia at 25°C. Supplementation with auxiliary free energy data allows the tabulation of standard electrode potentials in 1 m acid liquid ammonia solutions for 143 half-reactions involving 58 elements.

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Authors and Affiliations

  1. Department of Chemistry, The University of Texas, 78712, Austin, TX

    Steven G. Bratsch & J. J. Lagowski

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  1. Steven G. Bratsch
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  2. J. J. Lagowski
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Bratsch, S.G., Lagowski, J.J. Predicted and experimental standard electrode potentials in liquid ammonia at 25°C. J Solution Chem 16, 583–601 (1987). https://doi.org/10.1007/BF00646336

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  • DOI: https://doi.org/10.1007/BF00646336

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