Skip to main content
Log in

Molecular interaction of N-formylmorpholine with alkanols, a spectroscopic study

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

The interactions of N-formylmorpholine (NFM) with different alkanols were monitored using proton nuclear magnetic resonance and IR spectroscopy. It was found that the NFM interaction with alkanols decreases with increasing length and branching of the alkanols. A good correlation was obtained between the proton chemical shift and the volume of mixing of alkanols with NFM.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Stein,Hydrocarbon Process 52, 139 (1973).

    Google Scholar 

  2. E. Cenelli, S. Noe, and G. Paret,Hydrocarbon Process 51, 141 (1972).

    Google Scholar 

  3. G. Preusser, M. Stein, and J. Franzen,The Oil and Gas 71, 114 (1973).

    Google Scholar 

  4. V. F. Trefny and Erdoel Khole,3rd Gas Petrochem. 23, 337 (1970).

    Google Scholar 

  5. P. Gerhard, S. Martin, and R. Klaus,German Patent 1, 916, 155, (1970).

    Google Scholar 

  6. A. M. Awwad and F. I. Kanbour,J. Iraqi. Chem. Soc. 5, 99 (1980).

    Google Scholar 

  7. A. M. Awwad, A. M. North, and R. A. Pethrick,J. Chem. Soc. Faraday Trans. 11, 79, 449 (1983).

    Google Scholar 

  8. A. M. Awwad, F. I. Kanbour, and E. I. Allos,J. Chem. Thermodyn. 16, 733 (1984).

    Google Scholar 

  9. F. I. Kanbour, A. M. Awwad, and E. I. Allose, unpublished results.

  10. L. Pauling,The Nature of the Chemical Bond, 2nd edn., (Cornell University Press, New York, 1948).

    Google Scholar 

  11. G. C. Pimental and A. L. McClellan,The Hydrogen Bond, (Freeman, San Francisco, 1960).

    Google Scholar 

  12. S. N. Vingradov and R. H. Linnel,Hydrogen Bonding, (Reinhold New York, 1971).

    Google Scholar 

  13. K. Nakanishi and P. H. Solomon,Infrared Absorption Spectroscopy 2nd edn., (Holden-Day, San Francisco, 1977).

    Google Scholar 

  14. A. J. Treszczanowicz and G. C. Benson,J. Chem. Thermody. 11, 861 (1979).

    Google Scholar 

  15. F. Franks and D. J. G. Lves,Quart. Rev. 20, 1, (1966).

    Google Scholar 

  16. F. Smith and I. Brown,Aus. J. Chem. 26, 705 (1973).

    Google Scholar 

  17. A. Sacco and A. K. Rakshit,J. Chem. Thermodyn. 7, 257 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Salman, S.R., Awwad, A.M., Allos, E.I. et al. Molecular interaction of N-formylmorpholine with alkanols, a spectroscopic study. J Solution Chem 16, 567–570 (1987). https://doi.org/10.1007/BF00646334

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00646334

Key words

Navigation