Abstract
Available data on the solubility of silver chloride in aqueous solutions of HCl, NaCl, KCl, LiCl, and NH4Cl, along with potentiometric measurements of the activity of Ag+ in aqueous NaCl−NaClO4 mixtures, have been analyzed to obtain the thermodynamic properties of the (AgCl)0, AgCl −2 , AgCl 2−3 , and AgCl 3−4 complexes. Results obtained include the stability constants of the complexes and 25°C, the virial parameters needed to calculate the activity coefficients of the complexes and the heats of the reactions by which they are formed. These results are sued to calculate tables of recommended values for the solubility of silver chloride in the host solutions as a function of concentration from 0 to 150°C and to make a critical evaluation of the reliability of previously published data.
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References
Stability Constants of Metal-Ion Complexes, L. G. Sillen and A. E. Martell, eds., (Chemical Society, London, 1964), p. 280;Suppl. No. 1 (1971), p. 67.
R. M. Smith and A. E. Martell, inCritical Stability Constants, Vol. 4, (Plenum, New York, 1976).
Handbook of Metal Ligand Heats, 2nd edn., J. J. Christensen, D. J. Eatough, and R. M. Izatt, eds., (Dekker, New York, 1975).
V. V. Ivanenko and L. A. Pamfilova,Geochemistry International 12, 218 (1975).
T. M. Seward,Geochemica et Cosmichemica Acta 40, 1329 (1976).
K. S. Pitzer and G. Mayorga,J. Phys. Chem. 77, 2300 (1973).
K. S. Pitzer and J. J. Kim,J. Am. Chem. Soc. 96, 5701 (1974).
W. F. Linke, inSolubility of Inorganic and Metal-Organic Compounds, (Prentice Hall, Princeton, 1958).
W. Schierholz,Sitzber K. Acad. Wiss. (Wien) 101, 2b, 4 (1890).
W. E. Barlow,J. Am. Chem. Soc. 28, 1446 (1906).
G. S. Forbes,J. Am. Chem. Soc. 33, 1937 (1911).
G. S. Forbes and H. I. Cole,J. Am. Chem. Soc. 43, 2492 (1921).
J. Kendall and C. H. Sloan,J. Am. Chem. Soc. 47, 2306 (1925).
L. Dede and Th. Walther,Z. Anorg. Chem. 163, 185 (1927).
A. Pinkus and N. Berkelaiko,J. Chim. Phys. 27, 364 (1930).
A. Pinkus and M. Haugen,Bull. Soc. Chim. Belg. 45, 693 (1936).
A. Pinkus and A. M. Timmermans,Bull. Soc. Chim. Belg. 46, 461 (1937).
K. H. Lieser,Z. Anorg. Chem. 292, 97 (1937).
W. Erber and A. Schuhly,J. Prakt. Chem. 158, 176 (1941).
A. B. Garrett, M. V. Noble, and S. Miller,J. Chem. Ed. 19, 485 (1942).
S. Jaques,Helv. Chim. Acta. 29, 1041 (1946).
J. H. Jonte and D. S. Martin,J. Am. Chem. Soc. 74, 2052 (1952).
I. Leden,Svensk. Kim. Tidskr. 64, 249 (1952).
E. Berne and I. Leden,Svensk. Kim. Tidskr. 65, 88 (1953).
V. E. Mironov,Radiokhimiya 4, 707 (1962).
V. E. Mironov,Radiokhimiya 5, 118 (1963).
S. Ahrland and L. Johannson,Acta, Chem. Scand. 18, 2125 (1964).
Landolt-Bornstein,Physicalisch-Chemisch Tabellen IV, 1b, p. 80.
J. J. Fritz,J. Phys. Chem. 84, 2241 (1980).
J. J. Fritz,J. Phys. Chem. 85, 890 (1981).
B. B. Owen,J. Am. Chem. Soc. 60, 2229 (1938).
B. B. Owen and S. R. Brinkley,J. Am. Chem. Soc. 60, 2233 (1938).
E. A. Guggenheim and J. E. Prue,Trans. Faraday Soc. 50, 231, (1954).
F. D. Rossini, D. D. Wagman, W. H. Evans, S. Levine, and I. Jaffe,Natl. Bur. Stand. (U.S.), Circ. 500 (1952).
J. J. Fritz,J. Solution Chem. 13, 369 (1984).
J. E. Barney II, J. Argersinger, and C. A. Reynolds,J. Am. Chem. Soc. 73, 3785 (1951).
H. Chateau and B. Hervier,J. Chim. Phys. 54, 637 (1957).
G. A. Boss and A. H. Popel,Russ. J. Inorg. Chem. 12, 1098 (1967).
G. Bödlander and W. EberleinZ. Anorg. Chem. 39, 197 (1904).
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Fritz, J.J. Thermodynamic properties of chloro-complexes of silver chloride in aqueous solution. J Solution Chem 14, 865–879 (1985). https://doi.org/10.1007/BF00646296
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DOI: https://doi.org/10.1007/BF00646296