Abstract
The partial molar volumes at infinite dilution for a number of hydrochlorides and sodium salts of N-methyl derivatives of α, ω-aminocarboxylic acids in water at 25°C are measured and related to their van der Waals volumes. Results indicate that 4.96±0.48 water molecules hydrate a betaine hydrochloride. Volumes of proton ionization and interaction terms are evaluated. Group contributions to the partial molar volumes are also reported.
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Shahidi, F. Partial molar volumes of amino acid derivatives in water. J Solution Chem 12, 295–301 (1983). https://doi.org/10.1007/BF00646204
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DOI: https://doi.org/10.1007/BF00646204