Abstract
Raman and infrared line parameters of Zn(NO3)2-H2O systems ranging from dilute solutions (25°C) to ionic liquids of low water content (75°C) are reported. At 25°C the solutions contain a very low concentration of inner sphere [Zn(ONO2)(H2O)5]+, outer sphere [Zn(H2O)6]2+[NO3]−, Zn(H2O) 2+6 , and NO −3 (aq.). In the ionic liquids the ion triplet also exists. Manifestations of a change from the octahedral coordination of zinc to tetrahedral coordination when the water content is very low include the appearance of a 285 cm−1 band from the zinc nitrate bond and a shift to higher frequencies of the band from zinc-water.
Similar content being viewed by others
References
F. Franks and D. S. Reid, inWater, A Comprehensive Treatise, Vol. 2, F. Franks, ed. (Plenum, New York, 1973), p. 323.
H. Schneider, inSolute-Solvent Interactions, J. F. Coetzee and C. D. Ritchie, eds. (Marcel Dekker, New York, 1969), p. 301.
J. J. Padova, inModern Aspects of Electrochemistry, No 7, B. E. Conway and J. O'M. Bockris, eds. (Plenum, New York, 1972), p. 1.
D. Feakins and H. P. Bennetto, inHydrogen-Bonded Solvent Systems, A. K. Covington and P. Jones, eds. (Taylor and Francis, London, 1968), p. 235.
D. Feakins, inPhysico-Chemical Processes in Mixed Aqueous Solvents F. Franks, ed. (American Elsevier, New York, 1967), p. 71.
D. E. Irish, A. R. Davis, and R. A. Plane,J. Chem. Phys. 50, 2262 (1969).
D. E. Irish, inIonic Interactions, Vol. 2, S. Petrucci, ed.. (Academic Press, New York, 1971), p. 187.
A. R. Davis and D. E. Irish,Inorg. Chem. 7, 1699 (1968).
D. E. Irish and G. E. Walrafen,J. Chem. Phys. 46, 378 (1967).
A. T. G. Lemley and R. A. Plane,J. Chem. Phys. 57, 1648 (1972).
R. E. Hester and C. W. J. Scaife,J. Chem. Phys. 47, 5253 (1967).
R. E. Hester and R. A. Plane,J. Chem. Phys. 40, 411 (1964).
Y.-K. Sze and D. E. Irish,Can. J. Chem. 53, 427 (1975).
A. R. Davis and D. E. Irish,Can. J. Chem. 46, 943 (1968).
A. R. Davis, J. W. Macklin, and R. A. Plane,J. Chem. Phys. 50, 1478 (1969).
D. J. LockwoodJ. Chem. Soc. Faraday Trans. 2 71, 1440 (1975).
T. J. V. Findlay and M. C. R. Symons,J. Chem. Soc. Faraday Trans. 2 72, 820 (1976).
D. E. Irish, G. Chang, and D. L. Nelson,Inorg. Chem. 9, 425 (1970).
J. H. B. George, J. A. Rolfe, and L. A. Woodward,Trans. Faraday Soc. 49, 375 (1953).
A. Fratiello, V. Kubo, S. Peak, B. Sanchez, and R. E. Schuster,Inorg. Chem. 10, 2552 (1971).
J. T. Bulmer, D. E. Irish, and L. Odberg,Can. J. Chem. 53, 3806 (1975).
D. J. Cardin, inMTP International Review of Science, Inorganic Chemistry, Series, 1, Vol. 1, H. J. Emeleus and M. F. Lappert, eds. (Butterworths, London, 1972), p. 33.
L. E. Orgel,An Introduction to Transition-Metal Chemistry: Ligand Field Theory, 2nd ed. (Methuen, London, 1966), pp. 79–87.
D. J. Lockwood, J. Scott, W. L. Elsdon, and D. E. Irish,J. Raman Spectrosc. 2, 593 (1974).
A. R. Davis, D. E. Irish, R. B. Roden, and A. J. Weerheim,Appl. Spectrosc. 26, 384 (1972).
M. H. Brooker and D. E. Irish,Can. J. Chem. 49, 1510 (1971).
V. Ananthanarayanan,J. Chem. Phys. 52, 3844 (1970).
R. E. Hester and R. A. Plane,Inorg. Chem. 3, 768 (1964).
J. D. Riddell, D. J. Lockwood, and D. E. Irish,Can. J. Chem. 50, 2951 (1972).
L. G. Sillen and A. E. Martell,Stability Constants of Metal-Ion Complexes, Special Publications Nos. 17 and 25 (Chemical Society, London, 1964 and 1971).
T. G. Chang and D. E. Irish,J. Phys. Chem. 77, 52 (1973).
D. E. Irish, D. L. Nelson, and M. H. Brooker,J. Chem. Phys. 54, 654 (1971).
R. E. Hester and W. E. L. Grossman,Inorg. Chem. 5, 1308 (1966).
H. Brintzinger and R. E. Hester,Inorg. Chem. 5, 980 (1966).
W. Libus and I. Uruska,Inorg. Chem. 5, 256 (1965).
B. Taravel, G. Chauvet, P. Delorme, and V. Lorenzelli,J. Mol. Struct. 13, 283 (1972).
C. C. Addison and N. Logan, inAdvances in Inorganic Chemistry and Radiochemistry, Vol. 6, H. J. Emeleus and A. G. Sharpe, eds. (Academic Press, New York, 1964), p. 71.
C. C. Addison and B. M. Gatehouse,J. Chem. Soc., 613 (1960).
W. W. Ewing, J. J. McGovern, and G. E. Mathews, Jr.,J. Am. Chem. Soc. 55, 4827 (1933).
Y.-K. Sze, Ph.D. Thesis, University of Waterloo, Waterloo, Ontario, Canada (1973).
D. E. Irish and M. H. Brooker, inAdvances in Infrared and Raman Spectroscopy, Vol. 2, R. J. H. Clark and R. E. Hester, eds., (Heyden, London, 1976), Chap. 6, p. 212.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sze, YK., Irish, D.E. Vibrational spectral studies of ion-ion and ion-solvent interactions. I. Zinc nitrate in water. J Solution Chem 7, 395–415 (1978). https://doi.org/10.1007/BF00646111
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00646111