Journal of Solution Chemistry

, Volume 15, Issue 10, pp 803–809 | Cite as

EXAFS studies on the methanol and ethanol solutions of cobalt(II) bromides

  • Mitsuru Sano
  • Tetsuya Maruo
  • Yuichi Masuda
  • Hideo Yamatera
Article

Abstract

The results of an EXAFS investigation of methanol and ethanol solutions of CoBr2 are reported. The curve fitting analysis gives the coordination numbers and the Co−Br and Co-solvent distances. The results for both 0.2M and 3.8M CoBr2 in ethanol show the existence of [CoBr2(C2H5OH)2] as the dominant species, although a considerable amount of octahedral species also exists in the solutions. In 0.2 and 3.3M CoBr2 methanol solutions, the dominant species are [Co(CH3OH)6]2+ and [CoBr(CH3OH)5]+, respectively.

Key Words

Methanol ethanol cobalt(II) bromides EXAFS speciation 

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Copyright information

© Plenum Publishing Corporation 1986

Authors and Affiliations

  • Mitsuru Sano
    • 1
  • Tetsuya Maruo
    • 2
  • Yuichi Masuda
    • 2
  • Hideo Yamatera
    • 2
  1. 1.Laboratory of Inorganic Chemistry, College of General EducationNagoya UniversityNagoyaJapan
  2. 2.Department of Chemistry, Faculty of ScienceNagoya UniversityNagoyaJapan

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