Abstract
The limiting conductance of various salts of Na+, Ag+, Cu+, Cu2+ and Ph4As+ in acetonitrile-water (AN-H2O) and pyridine-water (Py−H2O) mixtures are reported. Single ion values are calculated for AN-H2O mixtures using the TATB assumption [λo(Ph 4 As +) = λo(Ph 4 B −)]. The trends observed for the limiting Walden products (λoη) of the electrolytes and individual ions are discussed in terms of specific ion-solvent interactions and the structural effects of the solvent mixtures.
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Singh, P., Macleod, I.D. & Parker, A.J. Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures. J Solution Chem 13, 103–119 (1984). https://doi.org/10.1007/BF00646043
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DOI: https://doi.org/10.1007/BF00646043