Skip to main content
SpringerLink
Log in

Isotope effects in aqueous systems. V. Partial molal enthalpies of solution of NaCl−H2O−D2O and related systems (5 to 75°C)1

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Solvent isotope effects on differential heats of solution of NaCl in HOH and DOD have been measured between 0.01 and 4m and from 5 to 40°C. These data are supplemented by integral heats of solution measured at 0.465m and from 5 to 75°C, and with heats of dilution over the same temperature range. The integral heat measurements include studies on otheralkali halides (KCl, NaI, NaBr), and the dilution measurements include some data for KCl. In the NaCl studies, particular attention was paid to the low-concentration region. Values of the partial molal enthalpiesL 1 adL 2 are derived for solution in both isotopic waters, and new values for the isotope effect on the standard enthalpy of solution ΔL s2 = (ΔH 02 ) d←w as a function of temperature are reported. Comparisons are made with previous work where possible. In contrast to statements made by earlier authors, examination of the low-concentration data reveals a\(\surd \overline m\) dependence within experimental error.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Water. A Comprehensive Treatise, F. Franks, ed., Vols. 1, 2, 3 (Plenum Press, New York, 1973).

    Google Scholar 

  2. E. M. Arnett and D. R. McKelvey, inSolute-Solvent Interactions, J. F. Coetzee and C. D. Ritchie, eds. (Interscience Publishers, New York, 1969), pp. 343–398.

    Google Scholar 

  3. H. L. Friedman and C. V. Krishnan, inWater. A Comprehensive Treatise, Vol. 3, F. Franks, ed. (Plenum Press, New York, 1973), pp. 1–118.

    Google Scholar 

  4. J. Bigeleisen, M. W. Lee, and F. Mandel,Ann. Rev. Phys. Chem. 24, 407 (1973).

    Google Scholar 

  5. G. Jancso and W. A. Van Hook,Chem. Rev. 74, 689 (1974).

    Google Scholar 

  6. L. I. Kleinman and M. Wolfsberg,J. Chem. Phys.,59, 2043 (1973);60, 4740, 4749 (1974).

    Google Scholar 

  7. A. Y. Fang and W. A. Van Hook,J. Chem. Phys. 60, 3513 (1974).

    Google Scholar 

  8. J. Bigeleisen,J. Chim. Phys. 61, 87 (1964).

    Google Scholar 

  9. J. Pupezin, G. Jakli, G. Jancso, and W. A. Van Hook,J. Phys. Chem. 76, 743 (1972).

    Google Scholar 

  10. G. Jakli, T. C. Chan, and W. A. Van Hook,J. Solution Chem. 4, 71 (1975).

    Google Scholar 

  11. M. Y. Schrier and E. E. Schrier,J. Chem. Thermodyn. 5, 811 (1973).

    Google Scholar 

  12. R. E. Kerwin, Ph.D. Dissertation, University of Pittsburgh, 1964.

  13. O. D. Bonner,J. Chem. Thermodyn. 3, 837 (1971).

    Google Scholar 

  14. P. R. Marshall and J. J. Katz,J. Inorg. Nucl. Chem. 36, 1589 (1974).

    Google Scholar 

  15. R. A. Robinson,J. Phys. Chem. 73, 3165 (1969).

    Google Scholar 

  16. R. A. Robinson,J. Solution Chem. 5, 819 (1973).

    Google Scholar 

  17. Y. C. Wu and H. L. Friedman,J. Phys. Chem. 70, 166 (1966).

    Google Scholar 

  18. P. R. Philip and J. R. Desnoyers,J. Solution Chem. 1, 353 (1972).

    Google Scholar 

  19. J. E. Desnoyers, R. Francescon, P. Picker, and C. Jolicoeur,Can. J. Chem. 49, 3460 (1971).

    Google Scholar 

  20. P. R. Philip, G. Perron, and J. E. Desnoyers,Can. J. Chem. 52, 1709 (1974).

    Google Scholar 

  21. J. L. Fortier, P. R. Philip, and J. E. Desnoyers,J. Solution Chem. 3, 523 (1974).

    Google Scholar 

  22. R. H. Wood, R. A. Rooney, and J. N. Braddock,J. Phys. Chem. 73, 1673 (1969).

    Google Scholar 

  23. A. A. Levine and R. H. Wood,J. Phys. Chem. 77, 2390 (1973).

    Google Scholar 

  24. Q. D. Craft, Ph.D. Thesis, University of Tennessee, 1975.

  25. M. H. Lietzke, ORNL Report No. 3259, Oak Ridge National Laboratory, Oak Ridge, Tennessee, April 1962.

  26. P. Debye and E. Hückel,Phys. Z. 24, 185, 334 (1923);25, 97 (1924).

    Google Scholar 

  27. H. S. Harned and B. B. Owen,The Physical Chemistry of Electrolyte Solution, 2nd ed. (Reinhold Publishing Corporation, New York, 1954), p. 379.

    Google Scholar 

  28. E. Hückel,Phys. Z. 26, 93 (1925).

    Google Scholar 

  29. R. W. Stoughton and M. H. Lietzke,J. Chem. Eng. Data 10, 254 (1965).

    Google Scholar 

  30. F. J. Millero,J. Phys. Chem. 74, 356 (1970).

    Google Scholar 

  31. Y. S. Choi and O. D. Bonner,Z. Phys. Chem. 87, 188 (1973).

    Google Scholar 

  32. G. S. Kell,J. Chem. Eng. Data 12, 66 (1967).

    Google Scholar 

  33. G. A. Vidulich, D. F. Evans, and R. L. Kay,J. Phys. Chem. 71, 656 (1967).

    Google Scholar 

  34. C. M. Criss and J. W. Cobble,J. Am. Chem. Soc. 83, 3223 (1961).

    Google Scholar 

  35. E. A. Gulbransen and A. L. Robinson,J. Am. Chem. Soc.,56, 2637 (1934).

    Google Scholar 

  36. V. B. Parker,Thermal Properties of Aqueous Uni-Univalent Electrolytes, NSRDSNBS2 (1965).

  37. D. D. Ensor and H. L. Anderson,J. Chem. Eng. Data 18, 205 (1973).

    Google Scholar 

  38. C. E. Vanderzee and L. J. Gier,J. Chem. Thermodyn. 6, 441 (1974).

    Google Scholar 

  39. Q. D. Craft and W. A. Van Hook,J. Solution Chem. 4, 923 (1975).

    Google Scholar 

  40. T. F. Young and J. S. Machin,J. Am. Chem. Soc. 58, 2252 (1936).

    Google Scholar 

  41. I. M. Klotz,Chemical Thermodynamics Prentice-Hall, Inc., Englewood Cliffs, New Jersey, 1957) p. 218.

    Google Scholar 

  42. D. H. Davies and G. C. Benson,Can. J. Chem. 43, 3100 (1965).

    Google Scholar 

  43. E. Lange and W. Martin,Z. Phys. Chem. A180, 233 (1937).

    Google Scholar 

  44. G. N. Lewis, M. Randall, K. S. Pitzer, and L. Brewer,Thermodynamics, 2nd ed. (McGraw-Hill, New York, 1961), pp. 375, 382.

    Google Scholar 

  45. C. V. Krishnan and H. L. Friedman,J. Phys. Chem. 74, 2356 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, University of Tennessee, 37916, Knoxville, Tennessee

    Quentin D. Craft (Tennesee Eastman Fellow, 1973–1974) & W. Alexander Van Hook

Authors
  1. Quentin D. Craft
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. W. Alexander Van Hook
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Abstracted in part from a thesis submitted by Q.D.C. in 1975 to the Chemistry Department, University of Tennessee, in partial fulfillment of the requirements for the Ph.D. degree in Chemistry.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Craft, Q.D., Van Hook, W.A. Isotope effects in aqueous systems. V. Partial molal enthalpies of solution of NaCl−H2O−D2O and related systems (5 to 75°C)1 . J Solution Chem 4, 901–922 (1975). https://doi.org/10.1007/BF00645888

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00645888

Key words

Search

Navigation