Abstract
The rate of the reaction Fe(CN) 4−6 +W(CN) 3−8 →Fe(CN) 3−6 +W(CN) 4−8 in aqueous solution has been studied at various temperatures and ionic strengths, in the presence of Group IA cations. The results, combined with earlier work on the ion pairing of these compounds, give an indication of the number of cations present in the activated complex, a number which increases steadily in going from Li+ to Cs+ as the associated cations. Activation parameters for the reaction at various total [M+] are also evaluated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
R. W. Chlebek and M. W. Lister,Can. J. Chem. 44, 437 (1966);45, 2411 (1967);49, 2943 (1971).
F. A. Jackman and M. W. Lister,J. Solution Chem. 4, 1023 (1975);5, 417 (1976).
J. N. Brønsted,Z. Phys. Chem. Leipzig 102, 169 (1922);115, 337 (1925). S. W. Benson,The Foundations of Chemical Kinetics (McGraw-Hill, New York, 1960), p. 525.
E. L. Goodenow and C. S. Garner,J. Am. Chem. Soc. 77, 5268 (1955).
A. G. MacDiarmid and N. F. Hall,J. Am. Chem. Soc. 76, 4222 (1954).
R. J. Campion, N. Purdie, and N. Sutin,Inorg. Chem. 3, 1091 (1964).
R. J. Lemire and M. W. Lister,J. Solution Chem. 5, 171 (1976).
A. Kosinska and Z. Wilczewska-Stasicka,Rocz. Chem. 31, 1029 (1957).
G. Brauer,Handbook of Preparative Inorganic Chemistry, 2nd ed., Vol. 2 (Academic Press, New York, 1965), p. 1509.
J. C. James and C. B. Monk,Trans. Faraday Soc. 46, 1041 (1950).
G. I. H. Hanania, D. H. Irvine, W. A. Eaton, and P. George,J. Phys. Chem. 71, 2022 (1967).
H. Baadsgaard and W. D. Treadwell,Helv. Chim. Acta 38, 1669 (1955).
L. D. C. Bok, J. G. Leipoldt, and S. S. Basson,J. Inorg. Nucl. Chem. 37, 2151 (1975).
A. C. Wahl,Z. Elektrochem. 64, 90 (1960).
R. J. Campion, C. F. Deck, P. King, and A. C. Wahl,Inorg. Chem. 6, 672 (1967).
V. P. Shvedov and G. F. Nichugovskii,Radiochemistry (USSR) 8, 62 (1966).
J. C. James,Trans. Faraday Soc. 45, 855 (1949).
G. I. H. Hanania and S. A. Israelian,J. Solution Chem. 3, 57 (1974).
R. A. Wynveen, J. L. Dye, and C. H. Brubaker,J. Am. Chem. Soc. 82, 4441 (1960).
P. Debye and E. Hückel,Phys. Z. 24, 185, 305 (1923).
J. Kielland,J. Am. Chem. Soc. 59, 1675 (1937).
S. Glasstone, K. J. Laidler, and H. Eyring,The Theory of Rate Processes (McGraw-Hill, New York, 1941).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lemire, R.J., Lister, M.W. Ion pairing and the rate of the reaction between hexacyanoferrate(II) and octacyanotungstate(V) ions. J Solution Chem 6, 429–442 (1977). https://doi.org/10.1007/BF00645837
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00645837