Abstract
Enthalpies of dilution of aqueous decyltrimethylammonium bromide have been measured from 0.56 to about .005 mol-kg−1 and from 50 to 225°C near the saturation pressure of water using a flow calorimeter. The changes of the stoichiometric osmotic and activity coefficients with temperature, the excess apparent molar heat capacity, and the apparent and partial relative molar enthalpies have been calculated from the data.
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D. F. Evans and P. J. Wightman,J. Colloid Interf. Sci. 86, 515 (1982).
D. G. Archer, H. J. Albert, D. E. White, and R. H. Wood,J. Colloid Interf. Sci. 100, 68 (1984).
D. F. Evans, M. Allen, B. W. Ninham, and A. Fouda,J. solution Chem. 13, 87 (1984).
H. J. Albert, Ph.D. Dissertation, University of Delaware (1984).
D. G. Archer, Ph.D. Dissertation, University of Delaware (1984).
P. Picker, E. Tremblay, and C. Jolicoeur,J. Solution Chem. 3, 377 (1974).
Sodev Inc., P. O. Box 1060, Sherbrooke, Quebec, Canada J1H 5LB.
T. E. Burchfield and E. M. Woolley,J. Phys. Chem. 88, 2149 (1984).
J. E. Desnoyers, G. Carron, R. De Lisi, D. Roberts, A. Roux, and G. Perron,J. Phys. Chem. 87, 1397 (1983).
J. A. Gates, Ph.D. Dissertation, University of Delaware (1984).
J. A. Gates and R. H. Wood,J. Chem. Thermodyn., accepted.
C. F. Gerald,Applied Numerical Analysis 2nd edn., (Addison Wesley, Reading, MA 1978).
L. Haar, J. S. Gallagher, and G. S. Kell,NBS/NRC Steam Tables: Thermodynamic and Transport Properties and Computer Programs for Vapor and Liquid States of Water in SI Units, (Hemisphere, Washington, 1984).
M. Uematsu and E. U. Franck,J. Phys. Chem. Ref. Data 9, 1291 (1980).
R. De Lisi, C. Ostiguy, G. Perron, and J. E. Desnoyers,J. Colloid Interf. Sci. 71, 147 (1979).
G. M. Musbally, G. Perron, and J. E. Desnoyers,J. Colloid Interf. Sci 48, 494 (1974).
J. E. Desnoyers, C. deVisser, G. Perron, and P. Picker,J. Solution Chem. 5, 605 (1976).
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Archer, D.G. Enthalpies of dilution from 50 to 225°C of aqueous decyltrimethylammonium bromide. J Solution Chem 15, 581–596 (1986). https://doi.org/10.1007/BF00645812
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DOI: https://doi.org/10.1007/BF00645812