Abstract
Tin (IV) chloride reacts with sulfolane (S) to form a cis-octahedral adduct SnCl4·S2. Solutions of lithium chloride and tin (IV) chloride in sulfolane contain the complex ions SnCl −5 and SnCl 2−6 at 1∶1 and 2∶1 mole ratios of constituents, respectively. The complexes are characterized by conductimetry and by Mössbauer, IR, and Raman spectroscopy.
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Doolan, P.C., Gore, P.H., Short, E.L. et al. Interaction of tin (IV) chloride with sulfolane and between tin (IV) chloride and lithium chloride in sulfolane solution. J Solution Chem 13, 313–319 (1984). https://doi.org/10.1007/BF00645704
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DOI: https://doi.org/10.1007/BF00645704