Abstract
The kinetics of piperidine replacement by pyridine at the pentacyano(piperidine)-ferrate(II) complex ion was studied under pseudo-first order conditions in binary aqueous mixtures of methanol, t-butanol, p-dioxane, and glycerol, from a mole fraction of co-solvent from 0 to about 0.15. The observed variations can be explained considering the degree of hydrophobic interaction between released ligand and water molecules which changes according to the structure-forming or struucture-breaking effect of added co-solvent on water.
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Salas, J.A., Katz, M. & Katz, N.E. Hydrophobic interaction effects on the kinetics of ligand substitution in binary aqueous mixtures at pentacyano(piperidine)ferrate(II) ion. J Solution Chem 12, 115–122 (1983). https://doi.org/10.1007/BF00645352
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DOI: https://doi.org/10.1007/BF00645352