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Enthalpies of dilution of aqueous systems containing hexamethylenetetramine and other nonelectrolytes

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Abstract

Enthalpies of dilution of aqueous systems containing hexamethylenetetramine, alone and in ternary system with each of mannitol, myoinositol, cyclohexanol, formamide, dimethylformamide, and trioxane have been determined. The data have been treated in terms of the Savage-Wood additivity principle and first estimates for the pairwise groups interaction enthalpies of N/N, CH2/N, CHOH/N, COHN/N and −O−/N have been made. The results are discussed in light of all other known group interaction enthalpies. The limitations and utilities of the Savage-Wood principle are reviewed.

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  1. Department of Chemistry, University of Delaware, 19711, Newark, DE

    Iran R. Tasker & Robert H. Wood

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Tasker, I.R., Wood, R.H. Enthalpies of dilution of aqueous systems containing hexamethylenetetramine and other nonelectrolytes. J Solution Chem 11, 729–747 (1982). https://doi.org/10.1007/BF00645339

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  • DOI: https://doi.org/10.1007/BF00645339

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