Abstract
Excess volumes of water-acetonitrile mixtures were obtained from measurements of density over the entire mole fraction range and at 5 degree intervals from 15 to 35°C. Partial molar excess volumes at the five temperatures, excess coefficients of thermal expansion at 25°C and partial molar excess expansibilities at 25°C were derived from the results. The values of the various volumetric properties are compared with data from the literature.
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Handa, Y.P., Benson, G.C. Thermodynamics of aqueous mixtures of nonelectrolytes. IV. Excess volumes of water-acetonitrile mixtures from 15 to 35°C. J Solution Chem 10, 291–300 (1981). https://doi.org/10.1007/BF00645018
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DOI: https://doi.org/10.1007/BF00645018