Abstract
Effects of pressure on ionization constants are described more simply by the use of solvent density rather than pressure. The recent ionization constants of metal sulfates in aqueous solution of Fisher and Fox are used to demonstrate greater predictability with density.
Similar content being viewed by others
References
F. H. Fisher and A. P. Fox,J. Solution Chem. 8, 309 (1979).
B. B. Owen and S. R. Brinkley,Chem. Rev. 29, 461 (1941).
E. U. Franck,Z. Phys. Chem. (Frankfurt)8, 107, 192 (1956).
W. L. Marshall and A. S. Quist,Proc. Nat'l. Acad. Sci. U.S. 58, 901 (1967).
A. S. Quist and W. L. Marshall,J. Phys. Chem. 72, 1536 (1968).
W. L. Marshall,J. Phys. Chem. 74, 346 (1970)
76, 720 (1972).
A. S. Quist,J. Phys. Chem. 74, 3396 (1970).
F. H. Sweeton, R. E. Mesmer, and C. F. Baes,J. Solution Chem. 3, 191 (1974).
W. L. Marshall,Rec. Chem. Prog. 30, 61 (1969).
M. H. Lietzke, Oak Ridge National Laboratory, Report ORNL-3259 (1962).
G. S. Kell and E. Whalley,J. Chem. Physics 62, 3496 (1975).
C-T Chen, R. A. Fine, and F. J. Millero,J. Chem. Physics 66, 2142 (1977).
C. W. Burnham, J. R. Holloway, and N. F. Davis,Amer. J. Sci.,267-A, 70 (1969).
International Formulation Committee 1967 Steam Tables; Committee established by the Sixth International Conference on the Properties of Steam (New York, October 1963).
G. S. Kell and E. Whalley,Phil. Trans. Roy. Soc. London 258, 565 (1965).
H. C. Helgeson and D. H. Kirkham,Amer. J. Sci. 274, 1089 (1974);
H. C. Helgeson and D. H. Kirkham,Amer. J. Sci. 274, 1089 (1974); (a)Table 3, (b)Table 8.
W. E. Sharp, Univ. of California Report No. UCRL-7118 (1962),
C. W. F. T. Pistorius and W. E. Sharp,Amer. J. Sci. 258, 757 (1960).
Handbook of Tables for Mathematics, 4th ed., The Chemical Rubber Co., Publ., Cleveland, Ohio, U.S.A., 1970.
A. S. Quist and W. L. Marshall,J. Phys. Chem. 72, 684 (1968).
L. A. Dunn and W. L. Marshall,J. Phys. Chem. 73, 2619 (1969).
L. B. Yeatts, L. A. Dunn, and W. L. Marshall,J. Phys. Chem. 75, 1099 (1971).
L. B. Yeatts and W. L. Marshall,J. Phys. Chem. 76, 1053 (1972).
F. H. Fisher,J. Phys. Chem. 66, 1607 (1962).
H. S. Dunsmore and J. C. James,J. Chem. Soc., 2925 (1951).
E. Inada, K. Shimizo, and J. Osugi,Nippon Kagaku Zasshi 92, 1096 (1971).
M. Eigen and K. Tamm,Elektrochem. 66, 93 (1962).
A. Bechteler, K. G. Breitschwerdt, and K. Tamm,J. Chem. Phys. 52, 2975 (1970).
F. J. Millero and W. L. Masterton,J. Phys. Chem. 78, 1287 (1974).
G. Atkinson and S. Petrucci,J. Phys. Chem. 70, 3122 (1974).
F. Garland, F.C. Patel, and G. Atkinson,J. Acoust. Soc. Am. 54, 996 (1973).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Marshall, W.L., Mesmer, R.E. On the treatment of pressure effects on lonization constants in aqueous solution. J Solution Chem 10, 121–127 (1981). https://doi.org/10.1007/BF00644994
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00644994