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Journal of Solution Chemistry

, Volume 10, Issue 2, pp 121–127 | Cite as

On the treatment of pressure effects on lonization constants in aqueous solution

  • William L. Marshall
  • R. E. Mesmer
Article

Abstract

Effects of pressure on ionization constants are described more simply by the use of solvent density rather than pressure. The recent ionization constants of metal sulfates in aqueous solution of Fisher and Fox are used to demonstrate greater predictability with density.

Key Words

Pressure density ionization constants volume changes water magnesium sulfate calcium sulfate cobalt and nickel sulfate 

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Copyright information

© Plenum Publishing Corporation 1981

Authors and Affiliations

  • William L. Marshall
    • 1
  • R. E. Mesmer
    • 1
  1. 1.Chemistry DivisionOak Ridge National LaboratoryOak RidgeUSA

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