Abstract
Velocity cross-correlation coefficients have been calculated for aqueous solutions of NiCl 2 and MgCl 2 up to concentrations of 4M. Examination of the concentration-dependence of these coefficients show that it is very similar for the two salts. There is no evidence for any special structural characteristics in NiCl 2 solutions. The velocity correlation technique is apparently not sensitive enough to detect the small amount of complexation that is thought to be present in NiCl 2 solutions.
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Geiger, A., Hertz, H.G. & Mills, R. Velocity correlations in aqueous electrolyte solutions from diffusion, conductance and transference data: Application to concentrated solutions of nickel chloride and magnesium chloride. J Solution Chem 10, 83–94 (1981). https://doi.org/10.1007/BF00644991
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DOI: https://doi.org/10.1007/BF00644991