Skip to main content
SpringerLink
Log in

Durability of Na2O-RO-SiO2 glasses in water

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The effect of divalent cation ions on chemical durability was studied in the base glasses 16Na2O-1ORO-74SiO2. In order to keep the same surface area, a fixed volume of glass powder was exposed to the corroding action of water. The amount of SiO2 and alkali extracted was determined. The chemical durability of glass was found to increase with increasing bond strength between the divalent cation and the non-bridging oxygen ion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. W. Morey, “The properties of glass” (Reinhold, New York, 1954) 101.

    Google Scholar 

  2. W. A. Weyl andE. C. Morboe, “The constitution of glasses: A Dynamic Interpretation”, Vol. II, Part 2, (Interscience, New York, 1967) p. 1100.

    Google Scholar 

  3. L. Holland, “The properties of glass surfaces” (Wiley, New York, 1964).

    Google Scholar 

  4. C. R. Das,Tram. Indian Ceram. Soc. 24(i) (1965) 12.

    Google Scholar 

  5. J. O. Isard andR. W. Douglas,J. Soc. Glass Tech. 33 (1949) 289.

    Google Scholar 

  6. M. A. Rana andR. W. Douglas,Phys. Chem. Glasses 2(6) (1961) 179.

    Google Scholar 

  7. Idem, ibid. 2(6) (1961) 196.

    Google Scholar 

  8. C. R. Das andR. W. Douglas,ibid. 8(1) (1967) 178.

    Google Scholar 

  9. T. M. El Shamy, J. Lewins andR. W. Douglas,Glass Tech. 13(3) (1972) 81.

    Google Scholar 

  10. D. M. Sanders andL. L. Hench,J. Amer. Ceram. Soc. 54 (1973) 373.

    Google Scholar 

  11. T. M. El Shamy, S. E. Morsi andS. A. Melibari, “Chemical durability of Na2O-Al2O3-SiO2, glass in relation to their membrane potentials”, Glass surfaces (19), (North Holland, Amsterdam, Oxford, 1975) pp. 801–11.

    Google Scholar 

  12. T. M. El Shamy, S. E. Morsi, H. D. Takieldin andA. A. Ahmed,ibid., pp. 241–50.

    Google Scholar 

  13. A. Paul andA. Youssefi,Glass Technol. 19(6) (1978) 166.

    Google Scholar 

  14. E. C. Ethridge, D. E. Clark andL. L. Hench,Phys. Chem. Glasses 20(2) (1979) 35.

    Google Scholar 

  15. Standard Methods of Test for Resistance of Glass Containers to chemical Attack, ASTM Desig. C225-54, American Society for Testing Materials.

  16. Indian Standard Method of Grading glass for alkalinity IS: 2303, Indian Standards Institution, Manak Bhavan, 9 Mathura Road, New Delhi 1 (India) (1963).

  17. P. B. Adams, M. E. Nordberg andH. V. Walters,Glass Technol. 5 (1964) 136.

    Google Scholar 

  18. G. Keppeler andM. Thomas-Welzow,Glastech. Ber. 11 (1933) 205.

    Google Scholar 

  19. E. Berger,J. Soc. Glass Technol. 20 (1936) T257.

    Google Scholar 

  20. A. K. Lyle,J. Amer. Ceram. Soc. 26 (1943) 202.

    Google Scholar 

  21. J. Enns,Glastech. Ber. 5 (1928) 449.

    Google Scholar 

  22. F. Y. Wang andF. V. Tooley,J. Amer. Ceram. Soc. 41 (1958) 521.

    Google Scholar 

  23. I. R. Beattie,Soc. Glass Technol. 37 (1953) T240.

    Google Scholar 

  24. R. H. Doremus, “Interdiffusion of hydrogen and alkali ions in a glass surface”, Glass surface (19) (North-Holland, Amsterdam, Oxford, 1975) 137–44.

    Google Scholar 

  25. Z. Boksay, G. Bouquet andS. Bobos,Phys. Chem. Glasses 8(4) (1967) 140.

    Google Scholar 

  26. R. J. Charles,J. Appl. Phys. 29 (1958) 1549.

    Google Scholar 

  27. D. E. Clark, M. F. Dilmore, E. C. Ethridge andL. L. Hench,J. Amer. Ceram. Soc. 59 (1976) 62.

    Google Scholar 

  28. M. L. Huggins andK. H. Suns,ibid. 26 (1943) 4.

    Google Scholar 

  29. C. R. Das,Glass Ind. 50 (1969) 422.

    Google Scholar 

  30. F. V. Tooley, “Handbook of Glass Manufacture”, Vol. II, (Ogden, New York, 36 NY, 1960) Table XIXC–III, p. 214.

  31. J. E. Stanworth, “Physical properties of glass” (Clarendon Press, Oxford, 1950) Table 8, p. 14.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Ceramic Engineering, Institute of Technology, Banaras Hindu University, 221005, Varanasi, India

    R. Pyare, M. R. C. Srivastava & P. Nath

Authors
  1. R. Pyare
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. R. C. Srivastava
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Nath
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pyare, R., Srivastava, M.R.C. & Nath, P. Durability of Na2O-RO-SiO2 glasses in water. J Mater Sci 17, 2932–2938 (1982). https://doi.org/10.1007/BF00644672

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00644672

Keywords

Search

Navigation