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Calorimetric investigations of the solvent effect on complex formation between pyridine derivatives and molecular iodine

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Abstract

The heats of solution of isoquinoline and 2,4-lutidine and heats of 1∶1 complex formation with molecular iodine inn-hexane, cyclohexane, CCl4, benzene, and chlorobenzene have been determined by the calorimetric method. The heats of transfer of the donor and donor-acceptor complex from nonsolvating medium (n-hexane) to the particular solvent were calculated and discussed in terms of donor and solvent properties and solute-solute-solvent interactions.

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Uruska, I., Inerowicz, H. Calorimetric investigations of the solvent effect on complex formation between pyridine derivatives and molecular iodine. J Solution Chem 9, 97–108 (1980). https://doi.org/10.1007/BF00644482

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  • DOI: https://doi.org/10.1007/BF00644482

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