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An alternative interpretation of the chemical shift of the water proton in aqueous tetraalkylammonium halide solutions at various temperatures

Journal of Solution Chemistry volume 7, pages 239–243 (1978)Cite this article

Abstract

An alternative explanation of the behavior of proton magnetic resonance chemical shifts of the water proton in aqueous tetraalkylammonium salt solutions is presented. It involves independent ion-solvent interactions and rapid exchange on the NMR time scale with the bulk water. Our explanation fits the known data and clearly shows why the observed chemical shift is linear with molality at low concentrations.

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Authors and Affiliations

  1. Department of Chemistry, University of Cincinnati, 45221, Cincinnati, Ohio

    George P. Kreishman

  2. Department of Chemistry and Chemical Engineering, Michigan Technological University, 49931, Houghton, Michigan

    Leslie Leifer

Authors
  1. George P. Kreishman
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  2. Leslie Leifer
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Kreishman, G.P., Leifer, L. An alternative interpretation of the chemical shift of the water proton in aqueous tetraalkylammonium halide solutions at various temperatures. J Solution Chem 7, 239–243 (1978). https://doi.org/10.1007/BF00644271

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  • DOI: https://doi.org/10.1007/BF00644271

Key words

  • Tetraalkylammonium halides
  • aqueous solutions
  • nuclear magnetic resonance
  • chemical shift

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