Journal of Solution Chemistry

, Volume 6, Issue 2, pp 111–115 | Cite as

Ion-solvent interaction in nonaqueous solutions. II. Spin-lattice relaxation times of23Na and133Cs

  • Yu. M. Kessler
  • A. I. Mishustin
  • A. I. Podkovyrin
Article

Abstract

The spin-lattice relaxation time (T1) of 23 Na was measured in solutions of NaClO 4 and (or) NaBr in formamide,N-methylformamide,N,N-dimethylformamide (DMF), MeCN, Me2CO, tetrahydrofuran (THF), and dimethyl sulfoxide (DMSO), and 133 Cs in a solution of CsCl in formamide. The values of (1/T1) 0 obtained by extrapolation are discussed in terms of current theories of quadrupolar magnetic relaxation of ionic nuclei. A correlation was found between (1/T1) 0 for 23 Na and Gutmann's donor numbers.

Key words

23Na and133Cs NMR relaxation ion-solvent interaction N-methylformamide N,N-dimethylformamide CH3CN acetone tetrahydrofuran dimethyl sulfoxide CsCl formamide Gutmann numbers 

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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • Yu. M. Kessler
    • 1
  • A. I. Mishustin
    • 1
  • A. I. Podkovyrin
    • 1
  1. 1.Moscow Institute of Chemical EngineeringMoscowUSSR

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