Theoretical and Experimental Chemistry

, Volume 26, Issue 3, pp 352–354 | Cite as

Co(II) and Co(III) macrocyclic boron-bearing dioximates

  • Ya. Z. Voloshin
  • N. A. Kostromina
  • A. Yu. Nazarenko
Brief Communications


Syntheses are reported for CoD3(BF)2 and [CoD3(BF)2]BF4,where H2D is dimethylglyoxime, α-benzyldioxime, or cyclohexanedione dioxime. The IR spectra at 400–4000 cm−1 have been measured, as have the electronic absorption spectra and the1H,13C,and11BNMR spectra; a comparison is made with the spectra of the analogous iron(II) complexes.


Iron Absorption Spectrum Cyclohexanedione Electronic Absorption Electronic Absorption Spectrum 
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Copyright information

© Plenum Publishing Corporation 1990

Authors and Affiliations

  • Ya. Z. Voloshin
    • 1
  • N. A. Kostromina
    • 1
  • A. Yu. Nazarenko
    • 1
  1. 1.Institute for General and Inorganic ChemistryUkrainian Academy of SciencesKiev

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