Abstract
Using a normalized perturbative, semi-classical approach, collision-induced rotational excitation rates of CO, OCS, SiO, HCN, HC3N due to H2 are computed. The calculated excitation rates for CO−H2 and OCS−H2 systems at 100 K are in good agreement with the results of close coupling approximation at low values ofJ, whereJ is the rotational quantum number. The rates are found to be very sensitive with respect to ortho and para states of H2.
Similar content being viewed by others
References
Berman, P. R.: 1978,Adv. Atom. Molec. Phys. 13, 57.
Davis, S. L., Boggs, J. E. and Mehrotra, S. C.: 1979,J. Chem. Phys. 71, 1418.
Gray, C. G.: 1968,Can. J. Phys. 46, 135.
Green, S. and Thaddeus, P.: 1976,Astrphys. J. 205, 766.
Green, S. and Chapman, S.: 1978,Astrophys. J. 37, 169.
Mehrotra, S. C. and Boggs, J. E.: 1975,J. Chem. Phys. 62, 1453.
Nerf, R. B. and Sonnenberg, M. A.: 1975,J. Mol. Spec. 58, 474.
Oka, T.: 1973,Adv. Atom. Molec. Phys. 91, 127.
Rabitz, H. and Gordon, R. G.: 1970,J. Chem. Phys. 53, 1815.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mehrotra, S.C. Collisional excitation of interstellar molecules due to H2: Linear molecules CO, OCS, SiO, HCN and HC3N in1Σstate. Astrophys Space Sci 71, 507–514 (1980). https://doi.org/10.1007/BF00639406
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00639406