Transition Metal Chemistry

, Volume 9, Issue 10, pp 377–379 | Cite as

Histidine-containing mixed amino acid and dipeptide copper(II) complexes. Cyclic voltammetric studies on the reduction in aqueous media

  • George Thomas
  • Panthappally S. Zacharias
Full Papers

Summary

Cyclic voltammetric studies on the reduction of the title complexes were carried out in aqueous media at HMDE. The histidine-containing mixed amino acid copper(II) complexes exhibit a relatively sharp reduction peak which is identified with an adsorption-controlled reduction process. The histidine-containing copper(II) dipeptide complexes undergo a one-electron reduction generating an intermediate copper(I) species which subsequently decomposes to Cu0. The mechanism of these processes is discussed. The cyclic voltammograms of these complexes are not complicated by adsorption processes.

Keywords

Copper Physical Chemistry Inorganic Chemistry Aqueous Medium Adsorption Process 

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References

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Copyright information

© Verlag Chemie GmbH 1984

Authors and Affiliations

  • George Thomas
    • 1
  • Panthappally S. Zacharias
    • 1
  1. 1.School of ChemistryUniversity of HyderabadHyderabadIndia

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