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Fresenius' Journal of Analytical Chemistry

, Volume 343, Issue 9–10, pp 717–718 | Cite as

Oxisolv® plus microwave — a new way for sample pretreatment and sample preparation

  • Jutta Köthe
  • Roland Bitsch
Symposium Papers

Summary

A new sample pretreatment procedure for water and waste water samples is presented. Complexing agents inhibit the determination of metals in instrumental analysis. These reagents often contain nitrogen or organic phosphate. During digestion with peroxodisulphate/alkali = Oxisolv® in combination with microwave heating in a closed Teflon-vessel, all N and P react to nitrate and phosphate. The resulting ions can be determined with photometric, AAS, voltammetric or other methods. NTA, EDTA, DTPA, TMT, TEA, CN and Tetra ToruMin as complexing agents were tested. In the case of Cr, Cu, Fe, Ni and Zn higher recoveries were obtained in comparison with the DIN-method (NTA as complexing agent). Due to MnO2 precipitation for Mn no values could be found.

Keywords

Precipitation Phosphate Nitrate Waste Water Microwave 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Koroleff F (1969) International Council for Exploration of the Sea, Council MeetingGoogle Scholar
  2. 2.
    Nydahl, F (1978) Water Research 12, 1123Google Scholar
  3. 3.
    Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlammuntersuchung, VCH Weinheim, DIN 38 406 E 22Google Scholar

Copyright information

© Springer-Verlag 1992

Authors and Affiliations

  • Jutta Köthe
    • 1
  • Roland Bitsch
    • 1
  1. 1.E. MerckDarmstadt 1Federal Republic of Germany

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