Chemistry of Heterocyclic Compounds

, Volume 27, Issue 1, pp 38–41 | Cite as

Oxidation-reduction characteristics of octahydrochalcogenoxanthenes and octahydroxanthylium cations

  • N. T. Berberova
  • A. F. Blinokhvatov
  • A. S. Archegova
  • E. S. Klimov
  • A. E. Shpakov
  • O. Y. Okhlobystin


Unstable radical-cations, which fragment according to the (−e, −H+, −e) scheme, are formed during the electrochemical oxidation of chalcogenooctahydroxanthenes. Free radicals (identified by ESR) are formed during the electrochemical reduction of the chalcogenooctahydroxanthylium cations.


Oxidation Organic Chemistry Free Radical Electrochemical Oxidation Electrochemical Reduction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. 1.
    N. T. Berberova, A. A. Bumber, V. B. Panov, and O. Yu. Okhlobystin,Dokl. Akad. Nauk SSSR,246, 108 (1979).Google Scholar
  2. 2.
    N. T. Berberova and O. Yu. Okhlobystin,Khim. Geterotsikl. Soedin., No. 8, 1011 (1984).Google Scholar
  3. 3.
    I. M. Sosonkin, A. P. Domarev, N. I. Kozhevnikova, and V. G. Kharchenko,Khim. Geterotsikl. Soedin., No. 3, 318 (1984).Google Scholar
  4. 4.
    N. N. Bubnov, S. P. Solodovnikov, A. I. Prokofev, and M. I. Kabachnik,Usp. Khim.,47, No. 6, 1048 (1978).Google Scholar
  5. 5.
    V. Kh. Sabanov, E. S. Klimov, I. V. Bogdanova, E. P. Trub, N. T. Berberova, and O. Yu. Okhlobystin,Khim. Geterotsikl. Soedin., No. 7, 970 (1986).Google Scholar
  6. 6.
    K. Esida,Electrooxidation in Organic Chemistry [Russian translation], Mir, Moscow (1987), p. 34.Google Scholar
  7. 7.
    S. K. Klimenko, N. N. Ivanov, and N. N. Sorokin,Zh. Org. Khim., No. 9, 2019 (1987).Google Scholar
  8. 8.
    Ya. P. Stradyn', R. A. Gavar, L. Kh. Baumane, L. M. Baider, B. A. Medynya, and A. M. Trushule,Khim. Geterotsikl. Soedin., No. 12, 1606 (1980).Google Scholar
  9. 9.
    A. T. Balaban and N. S. Barbulescu,Rev. Roum. Chim.,11, 109 (1966).Google Scholar
  10. 10.
    V. G. Kharchenko, S. K. Klimenko, and T. I. Krupina,Zh. Org. Khim., No. 3, 1344 (1967).Google Scholar
  11. 11.
    A. F. Blinokhvatov, O. V. Markovtseva, I. A. Shlaider, and V. G. Kharchenko,Khim. Geterotsikl. Soedin., No. 5, 640 (1981).Google Scholar
  12. 12.
    A. F. Blinokhvatov, “Investigations in the region of the chemistry of Β-cycloketols and the products from their transformations,” Candidate's Thesis, Saratov (1975), p. 101.Google Scholar
  13. 13.
    V. G. Kharchenko, N. M. Yartseva, and N. I. Kozhevnikova,Zh. Org. Khim., No. 7, 1551 (1971).Google Scholar
  14. 14.
    V. G. Kharchenko, T. I. Krupina, and A. A. Rassudova,Khim. Geterotsikl. Soedin., No. 2, 226 (1969).Google Scholar
  15. 15.
    V. G. Kharchenko and A. F. Blinokhvatov,Khim. Geterotsikl. Soedin., No. 12, 1615 (1978).Google Scholar

Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • N. T. Berberova
    • 1
  • A. F. Blinokhvatov
    • 1
  • A. S. Archegova
    • 1
  • E. S. Klimov
    • 1
  • A. E. Shpakov
    • 1
  • O. Y. Okhlobystin
    • 1
  1. 1.K. L. Khetagurov Severo-Osetinsk State UniversityVladikavkaz

Personalised recommendations