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Heteroatomic derivatives of aziridine. 15. Reaction of 1-(triethylsilyl)- and 1-[2-(trialkylsilyl)ethyl]-aziridines with thiols

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of 1-(triethylsilyl)aziridine with alkanethiols proceeds with splitting out of aziridine and the formation of (alkylthio)triethylsilanes. The reaction of 1-(triethylsilyl)aziridine with 2-mercaptoethanol leads to 2-(triethylsilyloxy)ethanethiol; the same reaction in a closed system leads to [2-(2-aminoethylthiol)ethoxy]triethylsilane. 1-[2-(Trialkylsilyl)ethyl]aziridines react with 2-mercaptoethanol and with mercapto carboyxlic acids with opening of the aziridine ring.

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See [1] for Communication 14.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 891–893, July, 1988.

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Voronkov, M.G., Knutov, V.I. Heteroatomic derivatives of aziridine. 15. Reaction of 1-(triethylsilyl)- and 1-[2-(trialkylsilyl)ethyl]-aziridines with thiols. Chem Heterocycl Compd 24, 730–732 (1988). https://doi.org/10.1007/BF00633163

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  • DOI: https://doi.org/10.1007/BF00633163

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