Abstract
The reaction of 1-(triethylsilyl)aziridine with alkanethiols proceeds with splitting out of aziridine and the formation of (alkylthio)triethylsilanes. The reaction of 1-(triethylsilyl)aziridine with 2-mercaptoethanol leads to 2-(triethylsilyloxy)ethanethiol; the same reaction in a closed system leads to [2-(2-aminoethylthiol)ethoxy]triethylsilane. 1-[2-(Trialkylsilyl)ethyl]aziridines react with 2-mercaptoethanol and with mercapto carboyxlic acids with opening of the aziridine ring.
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M. G. Voronkov, V. I. Knutov, and M. K. Butin, Khim. Geterotsikl. Soedin., No. 10, 1340 (1984).
M. G. Voronkov, G. I. Zelchan, and é. Ya. Lukevits, Silicon and Life [in Russian] Zinatne, Riga (1978), p. 362.
M. G. Voronkov, V. I. Knutov, L. M. Chudesova, I. D. Kalikhman, and N. P. Sokol'nikova, Khim. Geterotsikl. Soedin., No. 11, 1507 (1977).
N. S. Vyazankin, M. N. Bochkarev, L. P. Sanina, A. N. Egorochkin, and S. Yu. Khorshev, Zh. Obshch. Khim.,37, 2576 (1967).
M. G. Voronkov, V. I. Knutov, and L. M. Chudesova, USSR Author's Certificate No. 496,806; Byull. Izobret., No. 23, 190 (1984).
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See [1] for Communication 14.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 891–893, July, 1988.
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Voronkov, M.G., Knutov, V.I. Heteroatomic derivatives of aziridine. 15. Reaction of 1-(triethylsilyl)- and 1-[2-(trialkylsilyl)ethyl]-aziridines with thiols. Chem Heterocycl Compd 24, 730–732 (1988). https://doi.org/10.1007/BF00633163
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DOI: https://doi.org/10.1007/BF00633163