Abstract
It is shown that on the superacid cyclization of esters of bishomobicyclogeranylgeranic and E,E-bishomofarnesic acids fully cyclized hydroxyesters are formed in good yield, while on the interaction of esters of 6-hydroxy- and 6-acyloxy-15-bishomobicyclogeranylgeranic acids with a superacid no carbocyclization takes place.
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Literature cited
P. F. Vlad, N. D. Ungur, and V. B. Perutskii, Khim. Geterotsikl. Soedin., No. 3, 305–309 (1991).
P. F. Vlad, N. D. Ungur, and Nguen Van Khung, Khim. Prir. Soedin., No. 3, 346–353 (1990).
T. Norin and L. Westfelt, Acta Chem. Scand.,17, No. 6, 1828–1830 (1963).
N. N. Sukhanov, L. N. Grappel', V. V. Chetverikov, and L. A. Yanovskaya, Zh. Org. Khim.,21, No. 12, 2503–2506 (1985).
P. F. Vlad and G. V. Lazur'evskii, Bicyclic Diterpenoids [in Russian], Kishinev, RIO AN MSSR [Editing-Publishing Division of the Moldovian SSR Academy of Sciences] (1968).
P. F. Vlad and G. V. Lazur'evskii, Izv. AN MSSR, No. 12, 69–74 (1961).
J. H. Babler, J. Org, Chem.,41, No. 7, 1262–1264 (1976).
T. M. Khomenko, D. V. Korchagina, Yu. V. Gatilov, I. Yu. Bagryanskaya, and V. A. Barkhash, Zh. Org. Khim.,27, No. 3, 599–609 (1991).
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Institute of Chemistry, Moldovian Academy of Sciences, Kishinev. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 645–653, November–December, 1992.
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Ungur, N.D., Van Tuen, N., Popa, N.P. et al. Superacid cyclization of esters of some bishomoisoprenoid acids. Chem Nat Compd 28, 561–568 (1992). https://doi.org/10.1007/BF00630430
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DOI: https://doi.org/10.1007/BF00630430