Abstract
A four-stage synthesis has been performed of the optically active (S)-(−)-diprionyl acetate in the form of an equimolar mixture of erythro-(2S,3S,7SR)- and threo-(2R,3S,7SR)-2-acetoxy-3,7-dimethylpentadecanes from a readily available chiral compound — (S)-(+)-3,7-dimethylocta-1,6-diene — with an overall yield of 13%.
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Institute of Chemistry, Bashkir Scientific Center, Urals Branch, Russian Academy of Sciences, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 117–122, January–February, 1992.
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Odinokov, V.N., Ishmuratov, G.Y., Ladenkova, I.M. et al. Insect pheromones and their analogues. Chem Nat Compd 28, 98–102 (1992). https://doi.org/10.1007/BF00629804
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DOI: https://doi.org/10.1007/BF00629804