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Transition Metal Chemistry

, Volume 6, Issue 2, pp 79–82 | Cite as

Methylphenylphosphinate complexes with tri- and tetra-positive metal ions

  • Chester M. Mikulski
  • Joseph Unruh
  • Richard Rabin
  • Frank J. Iaconnianni
  • Louis L. Pytlewski
  • Nicholas M. Karayannis
Full Papers

Summary

A series of methylphenylphosphinate {mpp; [-O-P-Ph(Me)-O-]} complexes of the forms M(mpp)3 (M = Al, Ga, In, Sc, Y, Dy, Ti, V, Cr and Fe) and M(mpp)4 (M = Th or U) were made from the appropriate metal chloride and a large excess of MeO(Me)PhP(O) at elevated temperatures. Structures involving linear, ligand-bridged polymeric species are suggested on the basis of the i.r. and magnetic data.

Keywords

Chloride Physical Chemistry Inorganic Chemistry Elevated Temperature Large Excess 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Verlag Chemie GmbH 1981

Authors and Affiliations

  • Chester M. Mikulski
    • 1
  • Joseph Unruh
    • 1
  • Richard Rabin
    • 1
  • Frank J. Iaconnianni
    • 2
  • Louis L. Pytlewski
    • 2
  • Nicholas M. Karayannis
    • 3
  1. 1.Department of Chemistry and PhysicsBeaver CollegeGlensideUSA
  2. 2.Department of ChemistryDrexel UniversityPhiladelphiaUSA
  3. 3.Amoco Chemicals CorporationNapervilleUSA

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