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Rhodium(III) halide complexes with sulphur donors. The crystal structure ofmer-tris(o-ethylthiocarbamate)-trichlororhodium(III)acetone(1/1)

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Summary

The complexes [Rh(TC)3Cl3] · Me2CO and [Rh(TC)3X3] · 0.5 Me2CO (TC=O-ethylthiocarbamate; X=Br or I) have been prepared and characterized by i.r. and1H n.m.r. spectroscopy.

The crystal structure of [Rh(TC)3Cl3] · Me2CO has been determined by x-ray diffractometer data and refined to R=0.040. Crystals are monoclinic, space group P21, with a=9.101(5), b=15.785(8), c=8.776(5) Å, and β=103.00(3)°; Dx=1.57 gcn−3 for Z=2. The complex is monomeric with octahedral Rh. Relevant distances are Rh-Cl (trans to one another) 2.354(2) and 2.353(2) Å, Rh-Cl (trans to S) 2.388(2) Å; Rh-S (trans to one another) 2.376(3) and 2.369(3) Å, Rh-S (trans to Cl) 2.332(3) Å. There is intramolecular, and possibly intermolecular, hydrogen bonding in the structure.

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Authors and Affiliations

  1. Istituto di Chimica e Tecnologia dei Radioelementl del C.N.R., Padova, Italy

    Eleonora Forsellini & Umberto Casellato

  2. Istituto di Chimica Generale dell'Università, via Loredan 4, Padova, Italy

    Giuseppina Faraglia, Luciano Volponi & Rodolfo Graziani

Authors
  1. Eleonora Forsellini
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  2. Umberto Casellato
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  3. Giuseppina Faraglia
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  4. Luciano Volponi
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  5. Rodolfo Graziani
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Forsellini, E., Casellato, U., Faraglia, G. et al. Rhodium(III) halide complexes with sulphur donors. The crystal structure ofmer-tris(o-ethylthiocarbamate)-trichlororhodium(III)acetone(1/1). Transition Met Chem 9, 419–423 (1984). https://doi.org/10.1007/BF00624790

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  • DOI: https://doi.org/10.1007/BF00624790

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