Summary
Perrhenate(VII) was reductively nitrosylated using an excess of CN−, OH− and NH2OH · HCl, and from the reaction mixture K3[Re(NO)(CN)5] · 2H2O has been isolated. Its aqueous solution behaves as a 3∶1 electrolyte and its13C n.m.r. spectrum in D2O solution suggests that the complex molecule forms two types of isomeric structure arising from the two different modes of intramolecular hydrogen (deuterium) bonding of the two lattice water (D2O in the bulk solvent) molecules.
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Bhattacharyya, R., Roy, P.S. A very simple synthesis of K3[Re(NO)(CN)5] · 2 H2O directly from [ReO4]−: Existence of two structural isomers in aqueous medium as indicated by13C N.m.r. spectroscopy. Transition Met Chem 9, 281–284 (1984). https://doi.org/10.1007/BF00624476
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DOI: https://doi.org/10.1007/BF00624476