Skip to main content
SpringerLink
Log in

Polymetallic complexes: Part VI. Schiff base complexes of cobalt(II), copper(II), nickel(II), zinc(II), cadmium(II) and mercury(II)

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The doubly bidentate ON-NO donor Schiff base, prepared from salicylaldehyde and 4,4′-diaminodiphenylmethane forms complexes with 1∶1 metal: ligand stoichiometric ratios. The cobalt(II), copper(II) and nickel(II) complexes exhibit subnormal magnetic moments. All the six complexes possess high melting points and are sparingly soluble in common organic solvents. A dinuclear octahedral structure is proposed for the cobalt(II), copper(II), nickel(II) and zinc(II) complexes and a dinuclear tetrahedral configuration is suggested for the cadmium(II) and mercury(II) complexes on the basis of analytical, conductance, magnetic susceptibility, molecular weight, i.r. and electronic spectral data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. H. Holm and G. W. Everest jr,J. Am. Chem. Soc., 88, 2442 (1966).

    Google Scholar 

  2. J. C. Bailar and H. A. God winard,J. Am. Chem. Soc., 63, 2467 (1961).

    Google Scholar 

  3. D. G. Hodgson,Prog. Inorg. Chem., 19, 173 (1975).

    Google Scholar 

  4. R. Whyman and E. Hatfield,Transition Met. Chem., 5, 47 (1969).

    Google Scholar 

  5. B. Sahoo and J. Chakravarty,Ind. J. Chem., 20A, 431 (1981).

    Google Scholar 

  6. B. B. Mahapatra and S. K. Pujari,Chemical Tech. and Biotech. (UK), in press.

  7. B. B. Mahapatra, D. Panda and B. K. Patel,Acta Chim. (Hung), in press.

  8. B. B. Mahapatra and S. K. Pujari,Acta Chim. (Hung), in press.

  9. J. E. Covacis,Spectrochim. Acta, 23A, 183 (1967).

    Google Scholar 

  10. P. Teyssi and J. J. Charrettee,Spectrochim. Acta, 19, 1407 (1965).

    Google Scholar 

  11. K. Nakamoto,Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York, 1963.

    Google Scholar 

  12. I. Gamo,Bull. Chem. Soc., 34, 760 (1961).

    Google Scholar 

  13. J. R. Ferraro,Low Frequency Vibrations of Inorganic and Coordination Compounds, Plenum Press, New York, 1971.

    Google Scholar 

  14. A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968.

    Google Scholar 

  15. C. J. Ballhausen,Introduction to Ligand Field Theory, McGraw Hill, New York, p. 268 1962.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, G. M. College, Sambalpur-768004, Orissa, India

    Bipin B. Mahapatra & Debendra Panda

Authors
  1. Bipin B. Mahapatra
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Debendra Panda
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mahapatra, B.B., Panda, D. Polymetallic complexes: Part VI. Schiff base complexes of cobalt(II), copper(II), nickel(II), zinc(II), cadmium(II) and mercury(II). Transition Met Chem 9, 280–281 (1984). https://doi.org/10.1007/BF00624475

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00624475

Keywords

Search

Navigation