Summary
Cobalt(II), nickel(II), palladium(II) and platinum(II) complexes witho-(OCD),m-(MCD) andp-chlorophenyldithiocarbamate (PCD) ligands have been synthesised and characterised by chemical analyses, molecular weight determinations, conductance measurements, electronic and i.r. spectral studies. The thermal behaviour of the complexes has been studied by t.g. and d.t.a. techniques in a static air atmosphere and heats of reaction of different decomposition steps have been calculated from the d.t.a. curves. The thermal decomposition products of the complexes were identified by elemental analyses and i.r. spectra.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
G. D. Thorn and R. A. Ludwig,The Dithiocarbamates and Related Compounds, Elsevier, New York, 1962.
M. A. Par Bernard and M. M. Borel,Bull. Soc. Chim. Fr., 3066 (1969).
G. D'Ascenzo and W. W. Wendlandt,J. Therm. Anal., 1, 423 (1969).
S. V. Larinov and L. A. Kosareva,Thermal Analysis, Proc. 4th ICTA, Budapest, 1974, p. 877.
S. Kumar, N. K. Kaushik and I. P. Mittal,Thermal Analysis, Proc. 6th ICTA, Bayreuth, 1980, p. 137.
S. Kumar and N. K. Kaushik,Thermochimica Acta, 41, 19 (1980).
S. Kumar and N. K. Kaushik,Indian J. Chem., 20, 512 (1981).
S. Kumar and N. K. Kaushik,J. Thermal. Anal, 21, 3 (1981).
N. K. Kaushik, G. R. Chhatwal and A. K. Sharma,Thermochimica Acta, 58, 231 (1982).
N. K. Kaushik, R. P. Singh and H. S. Sangari,Thermal Analysis, Proc. 7th ICTA, Kingston, Ont., Canada, 1982, p. 482.
N. K. Kaushik and K. C. Jain,Thermal Analysis, Proc. 7th ICTA, Kingston, Ont., Canada, 1982, p. 492.
N. K. Kaushik, G. R. Chhatwal and A. K. Sharma,J. Therm. Anal., 26, 399 (1983).
B. Bhushan, A. K. Sharma and N. K. Kaushik,Bull. Soc. Chim. Fr. 1, 297 (1983).
H. L. Klopping and G. J. M. Van der Kerk,Rec. Trav. Chim., 70, 917 (1951).
M. L. Shankaranarayana and C. C. Patel,Anal. Chem., 33, 1398 (1961).
A. I. Vogel,A Text Book of Quantitative Inorganic Analysis, Longmans Green, London, 1964.
L. Erdey, Gravimetric Analysis, Vols. I and II, Pergamon, New York, 1965.
J. Chatt, L. A. Duncanson and L. M. Venanzi,Nature, 117, 1042 (1956).
P. Bonati and R. Ugo,J. Organometal. Chem., 10, 257 (1967).
G. E. Monoussakis, C. A. Tsipis and C. C. Hadjkostas,Can. J. Chem., 53, 1530 (1975).
T. N. Srivastava and V. Kumar,J. Organometal Chem., 107, 55 (1976).
G. St. Nikolov, N. Jordanov and K. Daskadova,Inorg. Nucl. Chem. Lett., 33, 1059 (1971).
C. O'Connor, J. D. Gilbert and G. Wilkinson,J. Chem. Soc. A, 84 (1969).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kaushik, N.K., Bhushan, B. & Sharma, A.K. BisN(chlorophenyl)dithiocarbamato complexes of cobalt(II), nickel(II), palladium(II) and platinum(II). Transition Met Chem 9, 250–255 (1984). https://doi.org/10.1007/BF00624466
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00624466