Summary
Addition reactions of [MNCl4]− (M = Os or Ru) with ligands L or L′ to give [MNCl4 · L]− or [(MNCl4)2L′]2− (L = pyridine, pyridine-N-oxide,iso-quinoline or DMSO; L′ = hexamethylenetetramine, pyrazine or dioxan) are described. With NCO−, [OsNCl5]− gives [OsN(NCO)5]2− but NCS− gives a thionitrosyl complex, [Os(NS)(NCS)5]2−. Reactions of OsNCl3(AsPh3)2 with pyridine, 1,10-phenanthroline and tertiary phosphites and phosphinites have been studied, as have reactions of triphenylphosphine with OsOCl4 andtrans- [MO2Cl4]2− (M = Os or Ru). The nitrido-iodo complexes [OsNI4]− and OsNI3, (SbPh3)2 are also reported.
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Wright, M.J., Griffith, W.P. Studies on transition-metal nitrido and oxo complexes. Part VII(1). Substituted nitrido complexes of osmium and ruthenium. Transition Met Chem 7, 53–58 (1982). https://doi.org/10.1007/BF00623810
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DOI: https://doi.org/10.1007/BF00623810