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Rhenium. Part XVI. Ammine and pyridine compounds of zinc and cadmium containing coordinated perrhenate

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Summary

[Zn(NH3)4](ReO4)2 and [Cd(NH3)4](ReO4)2 have been prepared from M(ReO4)2 and aqueous ammonia. The tetrapyridine compounds [Zn(py)4(ReO4)2] and [Cd(py)4(ReO4)2] have been obtained by reacting M(NO3)2 with aqueous pyridine followed by the addition of HReO4. Pyrolysis of these complexes gives [Zn(NH3)2(ReO4)2], [Cd(NH3)2(ReO4)2], [Zn(py)2(ReO4)2] and [Cd(py)2(ReO4)2] respectively. The kinetics of the decomposition steps: [ML4(ReO4)2] → [ML2(ReO4)2] → M(ReO4)2 have been studied from the t.g.a. curves. I.r. and Raman spectral and x-ray powder diffraction studies indicate that all the pyridine complexes and the two diammine complexes contain coordinated perrhenate, while the two tetrammine complexes contain ionic perrhenate.

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Author notes

  1. Mukti B. Sarkar

    Present address: Department of Chemistry, Jamshedpur Regional Institute of Technology, Jamshedpur, Bihar, India

Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, Kharagpur, 721 302, West Bengal, India

    Mukul C. Chakravorti & Mukti B. Sarkar

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  1. Mukul C. Chakravorti
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  2. Mukti B. Sarkar
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Chakravorti, M.C., Sarkar, M.B. Rhenium. Part XVI. Ammine and pyridine compounds of zinc and cadmium containing coordinated perrhenate. Transition Met Chem 7, 19–22 (1982). https://doi.org/10.1007/BF00623801

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  • DOI: https://doi.org/10.1007/BF00623801

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