Transition Metal Chemistry

, Volume 11, Issue 11, pp 403–405 | Cite as

Thiocarboxamide complexes of rhodium, copper, palladium and platinum. The synthesis of [CuX(C4H4NCSNHCO2Et)(MPh3)2] (X = Cl or Br; M = As or P), [RhCl(MeC6H4CSNHCO2Et)2(PPh3)] and [M(MeC6H4CSNHCO2Et)2(PPh3)2] (M = Pd or Pt)

  • Veena Chauhan
  • Sheo K. Dikshit
Full Papers


Reaction ofN-ethoxycarbonylpyrrole-1-thiocarboxamide (EPTH) with [CuX(MPh3)3] yields [CuX(EPTH)(MPh3)2] (X = Cl or Br; M = As or P) and ofN-ethoxycarbonyltoluene-4-thiocarboxamide (ETTH) with [RhICl(PPh3)3], [Pd0(PPh3)4] and [Pt0(PPh3)4] yields [RhICl(ETTH)2(PPh3)], [Pd0(ETTH)2(PPh3)2] and [Pt0(ETTH)2(PPh3)2], respectively. The complexes have been characterised by analytical, i.r., electronic and n.m.r. spectral and magnetic measurements. All are tetrahedral except [RhCl(ETTH)2(PPh3)], which is square planar (trans).


Copper Physical Chemistry Platinum Inorganic Chemistry Palladium 
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Copyright information

© VCH Verlagsgesellschaft mbH 1986

Authors and Affiliations

  • Veena Chauhan
    • 1
  • Sheo K. Dikshit
    • 1
  1. 1.Department of ChemistryIndian Institute of TechnologyKanpur, 208016, U.P.India

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