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Transition Metal Chemistry

, Volume 11, Issue 11, pp 403–405 | Cite as

Thiocarboxamide complexes of rhodium, copper, palladium and platinum. The synthesis of [CuX(C4H4NCSNHCO2Et)(MPh3)2] (X = Cl or Br; M = As or P), [RhCl(MeC6H4CSNHCO2Et)2(PPh3)] and [M(MeC6H4CSNHCO2Et)2(PPh3)2] (M = Pd or Pt)

  • Veena Chauhan
  • Sheo K. Dikshit
Full Papers

Summary

Reaction ofN-ethoxycarbonylpyrrole-1-thiocarboxamide (EPTH) with [CuX(MPh3)3] yields [CuX(EPTH)(MPh3)2] (X = Cl or Br; M = As or P) and ofN-ethoxycarbonyltoluene-4-thiocarboxamide (ETTH) with [RhICl(PPh3)3], [Pd0(PPh3)4] and [Pt0(PPh3)4] yields [RhICl(ETTH)2(PPh3)], [Pd0(ETTH)2(PPh3)2] and [Pt0(ETTH)2(PPh3)2], respectively. The complexes have been characterised by analytical, i.r., electronic and n.m.r. spectral and magnetic measurements. All are tetrahedral except [RhCl(ETTH)2(PPh3)], which is square planar (trans).

Keywords

Copper Physical Chemistry Platinum Inorganic Chemistry Palladium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© VCH Verlagsgesellschaft mbH 1986

Authors and Affiliations

  • Veena Chauhan
    • 1
  • Sheo K. Dikshit
    • 1
  1. 1.Department of ChemistryIndian Institute of TechnologyKanpur, 208016, U.P.India

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