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Transition Metal Chemistry

, Volume 8, Issue 5, pp 273–276 | Cite as

Equilibria and kinetics of electron transfer between tris (4,4′-dimethyl-2,2′-bypyridine)-osmium(III)/-osmium(II) and iron(III)/iron(II) in aqueous mixtures of acetone and acetonitrile

  • Marco Vincenti
  • Edmondo Pramauro
  • Ezio Pelizzetti
Full Papers

Summary

The equilibrium and the kinetics of the title reaction have been investigated in various acetone and acetonitrile aqueous mixtures, by the stopped-flow spectrophotometric technique. The dependence of the reorganization energy on the solvent parameters is discussed.

Keywords

Iron Physical Chemistry Acetone Inorganic Chemistry Acetonitrile 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Verlag Chemie GmbH 1983

Authors and Affiliations

  • Marco Vincenti
    • 1
  • Edmondo Pramauro
    • 1
  • Ezio Pelizzetti
    • 1
  1. 1.Istituto di Chimica AnaliticaUniversità di TorinoTorinoItaly

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