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Iron(II) carbonyl complexes containing xanthate, dithiocarbamate or dithiophosphate ligands

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Summary

Starting from Fe(CO)4I2, octahedral FeII carbonyl derivatives of the types Fe(CO)2(xan)2, Fe(CO)3(xan)I and Fe(CO)3(dtc)I were prepared (xan = xanthate, dtc = dithiocarbamate). Infrared evidence was obtained for the formation of Fe(CO)2(dtp)2 complexes (dtp = dithiophosphate). The dixanthate complexes are also formed from FeII salts and potassium xanthates by CO absorption in MeOH/H2O solution.

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Authors and Affiliations

  1. Research Group for Petrochemistry of the Hungarian Academy of Sciences, H-8201, Veszprém, Hungary

    János Takács & László Markó

Authors
  1. János Takács
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  2. László Markó
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Takács, J., Markó, L. Iron(II) carbonyl complexes containing xanthate, dithiocarbamate or dithiophosphate ligands. Transition Met Chem 9, 10–12 (1984). https://doi.org/10.1007/BF00620719

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