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Reactions of the dinitrogen complextrans-[ReCl(N2)(dppe)2] with thiolate compounds and with carbon bisulphide

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Summary

The complextrans-[ReCl(N2)(dppe)2], (1) reacts with the thiolate salts Li[SC6H4Me-4], Tl[SC6H4Me-4] and [Pb(SBu-t)2] to yield [ReCl(SC6H4Me-4)(dppe)2], [Re(SC6H4Me-4) (dppe)2] and [{ReO(dppe)}2(μ-Cl)(μ-S)(μ-SBu-t)] (tentative formulation), respectively. The [ReCl(η2-CS2)(dppe)2] complex appears to be formed by reaction of (1) with CS2.

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Authors and Affiliations

  1. Centro de Química Estrutural, Complexe I, Institute Superior Técnico, Av. Rovisco Pais, 1096, Lisboa, Codex, Portugal

    Armando J. L. Pombeiro

  2. AFRC Unit of Nitrogen Fixation, University of Sussex, BNI 9RQ, Falmer, Brighton, UK

    Raymond L. Richards

Authors
  1. Armando J. L. Pombeiro
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  2. Raymond L. Richards
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Pombeiro, A.J.L., Richards, R.L. Reactions of the dinitrogen complextrans-[ReCl(N2)(dppe)2] with thiolate compounds and with carbon bisulphide. Transition Met Chem 10, 463–466 (1985). https://doi.org/10.1007/BF00620710

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  • DOI: https://doi.org/10.1007/BF00620710

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