Summary
The synthesis, characterization and electrochemical behaviour of a new series of copper(II) complexes derivated from substituted anilines and bromosalicylaldehydes have been studied.
The complexes show a square-plane stereochemistry in solution. The reduction potentials depend on the substitutents in the salicylaldehydes and on the precursor anilines. The evaluation of kinetic parameters show a single stage one-electron transfer.
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Araya, L.M., Vargas, J.A. & Costamagna, J.A. Ligand influence on the redox properties of some copper(II) complexes with schiff bases derived from bromosalicylaldehydes and methyl or chloro-substituted anilines. Transition Met Chem 11, 312–316 (1986). https://doi.org/10.1007/BF00620654
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DOI: https://doi.org/10.1007/BF00620654