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Nickel(II) and cobalt(II) complexes of the hydrazide of 1-naphthylacetic acid

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Summary

The hydrazide of 1-naphthylacetic acid forms both bis- and tris-(ligand) high-spin nickel(II) and cobalt(II) complexes possessing an octahedral configuration. The compositions of the complexes are influenced not only by the metal-ligand stoichiometry but also by the nature of the inorganic anion. A physico-chemical investigation showed that the ligand is neutral and bidentate, coordinated through amido-nitrogen and carbonyl oxygen. The compounds were characterized by elemental analysis, magnetic measurements, i.r. and diffuse-reflection spectra and molar conductivity.

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Authors and Affiliations

  1. Faculty of Chemistry, State University, Uzhgorod, USSR

    Stepan Yu. Chundak

  2. Faculty of Sciences, University of Novi Sad, Ilije Djuričića 4, 21000, Novi Sad, Yugoslavia

    Vukadin M. Leovac, Dušanka Ž. Obadović & Dragoslav M. Petrović

Authors
  1. Stepan Yu. Chundak
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  2. Vukadin M. Leovac
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  3. Dušanka Ž. Obadović
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  4. Dragoslav M. Petrović
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Chundak, S.Y., Leovac, V.M., Obadović, D.Ž. et al. Nickel(II) and cobalt(II) complexes of the hydrazide of 1-naphthylacetic acid. Transition Met Chem 11, 308–312 (1986). https://doi.org/10.1007/BF00620653

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  • DOI: https://doi.org/10.1007/BF00620653

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