Abstract
In this article the application of tunable dye lasers to desorption phenomena is illuminated. These lasers provide radiation continuously tunable from 105 nm in the vacuum ultraviolet to about 10 μm in the mid-IR. By employing either laser induced fluorescence (LIF) or resonance enhanced multiphoton ionization (REMPI) spectroscopy almost all diatomic and many polyatomic molecules can be probed with the sensitivity required to detect desorbing molecules under UHV conditions. The spectral resolution of the lasers is sufficiently high that rotational state selectivity is achieved. Recent developments permit in addition the velocity distributions of molecules to be determined with internal quantum state resolution. Therefore very detailed information about the molecular dynamics has been obtained. In most experiments so far reactive recombinations off surfaces have been investigated. In this paper special emphasis will be given to the recombination of hydrogen on copper and palladium surfaces. For these systems very detailed data about the internal state populations at various surface temperatures have been obtained. The rotational cooling previously observed in molecular beam scattering has also been established for desorption. Strong vibrational excitation has been observed, which in the case of desorption from copper may be associated with the recombination dynamics, whereas for desorption of D2 from Pd(100) a molecular precursor state might be responsible. By measuring the velocity distribution in each quantum state, the complete energetics of the desorbing molecules has been determined. Some first experiments on laser induced desorption with state selective detection of the desorbing molecules will also be discussed. Finally, making use of the polarization analysis of the signal, alignment effects in the desorption can be observed, permitting observation of molecular dynamics with a “magnifying glass”.
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D. Menzel: InKinetics of Interface Reactions, Springer Ser. Surf. Sci., Vol.8, ed. by M. Grunze, H.J. Kreuzer (Springer, Berlin, Heidelberg 1987) p. 2ff.
H.P. Steinrück, K.D. Rendulic, A. Winkler: Surf. Sci.154, 99 (1985); Surf. Sci.185, 469 (1987)
K.D. Rendulic, A. Winkler, H. Karner: J. Vac. Sci. Techn. A5, 488 (1987)
G. Comsa, R. David: Surf. Sci. Rep.5, 145 (1985)
H. Zacharias, M.M.T. Loy, P. Roland: Phys. Rev. Lett.49, 1790 (1982)
J. Misewich, H. Zacharias, M.M.T. Loy: Phys. Rev. Lett.55, 1919 (1985)
W. Allison, B. Feuerbacher: Phys. Rev. Lett.45, 2040 (1980)
J.A. Barker, D.J. Auerbach: Surf. Sci. Rep.4, 1 (1985)
M.C. Lin, G. Ertl: Ann. Rev. Phys. Chem.37, 587 (1986)
C.T. Rettner, D.J. Auerbach: J. Electr. Spectr. Rel. Phen.45, 335 (1987)
P.L. Houston, R.P. Merrill: Chem. Rev. (in press)
D.M. Newns: Surf. Sci.171, 600 (1986)
J.W. Gadzuk, J.K. Norskov: J. Chem. Phys.81, 2828 (1984)
J.W. Gadzuk, S. Holloway: Phys. Scr.32, 413 (1985)
J.W. Gadzuk: Surf. Sci.184, 483 (1987)
P. Haochang, T.C.M. Horn, A.W. Kleyn: Phys. Rev. Lett.57, 3035 (1986)
R.R. Cavanagh, D.S. King: Phys. Rev. Lett.47, 1829 (1981)
J.C. Tully, M.J. Cardillo: Science223, 445 (1984)
W. Brenig, H. Kasai, H. Müller: Surf. Sci.161, 608 (1985)
J.W. Gadzuk: J. Electr. Spectr. Rel. Phen.45, 371 (1987)
J.C. Tully: InKinetics of Interface Reactions, Springer Ser. Surf. Sci., Vol.8, ed. by M. Grunze, H. J. Kreuzer (Springer, Berlin, Heidelberg 1987) p. 37ff.
D.J. Doren, J.C. Tully: Langmuir (in press)
W. Brenig, D. Menzel (eds.):Desorption Induced by Electronic Transitions, DIET II, Springer Ser. Surf. Sci. Vol. 4 (Springer, Berlin, Heidelberg 1985)
D. Weide, P. Andresen, H.-J. Freund: Chem. Phys. Lett.136, 106 (1987)
F. Budde, A.V. Hamza, P.M. Ferm, G. Ertl, D. Weide, P. Andresen, H.-J. Freund: Phys. Rev. Lett.60, 1518 (1988)
R. Wallenstein: InLaser Handbook, Vol.3, ed. M.L. Stitch (North-Holland, Amsterdam 1979)
R.W.B. Pearse, A.G. Gaydon:The Identification of Molecular Spectra, 4th ed. (Chapman and Hall, London 1976)
T.J. Chuang, H. Seki, I. Hussla: Surf. Sci.158, 525 (1985)
M.P. Casassa, E.J. Heilweil, J.C. Stephenson, R.R. Cavanagh: J. Chem. Phys.84, 2361 (1986)
P. Esherick, R.J.M. Anderson: Chem. Phys. Lett.70, 621 (1980)
D.S. Bethune, A.C. Luntz: Appl. Phys. B40, 107 (1986)
R.J. Seymour, F. Zernicke: Appl. Phys. Lett.28, 705 (1976)
K. Kato: IEEE J. QE-20, 698 (1984); QE-21, 119 (1985)
W. Hartig, W. Schmidt: Appl. Phys.18, 235 (1979)
P. Rabinowitz, A. Kaldor, R. Brickman, W. Schmidt: Appl. Opt.15, 2005 (1976)
R. Frey, F. Pradere, J. Lukasik, J. Ducuing: Opt. Commun.22, 355 (1977)
A.L. Harris, N.J. Levinos: Appl. Opt.26, 3996 (1987)
P. Rabinowitz, B.N. Perry, N. Levinos: IEEE J. QE-22, 797 (1986)
W. Heuer, H. Zacharias: IEEE J. Quant. Electron. (in press)
H. Wallmeier, H. Zacharias: Appl. Phys. B45, 236 (1988) and references therein
J.F. Reintjes:Nonlinear Optical Parametric Processes in Liquids and Gases (Academic, New York 1984)
C.R. Vidal: InTunable Lasers, ed. by L.F. Mollenhauer, J.C. White, Topics Appl. Physics, Vol. 59 (Springer, Berlin, Heidelberg 1987) p. 57ff.
R. Hilbig, R. Wallenstein: IEEE J. QE-17, 1566 (1981)
R. Hilbig, R. Wallenstein: QE-19, 194 (1983)
R. Hilbig, R. Wallenstein: QE-19, 1759 (1983)
R. Hilbig, R. Wallenstein: Appl. Opt.21, 913 (1982)
R. Hilbig, R. Wallenstein: Opt. Comm.44, 283 (1983) and references therein
W. Zapka, D. Cotter, U. Brackmann: Opt. Comm.36, 79 (1981)
G. Hilber, A. Lago, R. Wallenstein: J. Opt. Soc. Am. B4, 1753 (1987) and references therein
H. Rottke, H. Zacharias: Phys. Rev. A33, 736 (1986)
L. Cabaret, C. Delsart, C. Blondel: Opt. Commun.61, 116 (1987)
A. Lago: Thesis, Universität Bielefeld, 1987
S.H. Lin, Y. Fujimura, H.J. Neusser, E.W. Schlag:Multiphoton Spectroscopy of Molecules (Academic, Orlando 1984)
S.V. Filseth, R. Wallenstein, H. Zacharias: Opt. Commun.23, 231 (1977)
S.T. Pratt, P.M. Dehmer, J.L. Dehmer: J. Chem. Phys.78, 4315 (1983) and references therein
A. Sur, C.V. Ramana, S.D. Colson: J. Chem. Phys.83, 904 (1985)
R.D. Johnson III, G.R. Long, J.W. Hudgens: J. Chem. Phys.87, 1977 (1987)
V.S. Letokhov:Laser Photoionization Spectroscopy (Academic, Orlando 1987)
G. Comsa, R. David, B.-J. Schumacher: Surf. Sci.85, 45 (1979)
J. Häger, Y.R. Shen, H. Walther: Phys. Rev. A31, 1962 (1985)
J.B. Halpern, H. Zacharias, R. Wallenstein: J. Mol. Spectr.79, 1 (1980)
W. Meier, H. Rottke, H. Zacharias, K.H. Welge: J. Chem. Phys.83, 4360 (1985)
H. Rottke, H. Zacharias: J. Chem. Phys.83, 4831 (1985)
G. Herzberg:Molecular Spectra and Molecular Structure. I. Spectra of Diatomic Molecules (van Nostrand Reinhold, New York 1950) p. 133ff.
G.D. Kubiak, J.E. Hurst, H.G. Rennagel, G.M. McClelland, R.N. Zare: J. Chem. Phys.79, 5163 (1983)
A.W. Kleyn, A.C. Luntz, D.J. Auerbach: Surf. Sci.117, 33 (1982)
J. Segner, H. Robota, W. Vielhaber, G. Ertl, F. Frenkel, J. Häger, W. Krieger, H. Walther: Surf. Sci.131, 273 (1983)
M. Asscher, W.L. Guthrie, T.-H. Lin, G.A. Somorjai: J. Chem. Phys.78, 6992 (1983)
R.J. Hamers, P.L. Houston, R.P. Merrill: J. Chem. Phys.83, 6045 (1985); J. Chem. Phys. (in press)
F. Frenkel, J. Häger, W. Krieger, H. Walther, G. Ertl, J. Segner, W. Vielhaber: Chem. Phys. Lett.90, 225 (1982)
A. Mödi, T. Gritsch, F. Budde, T.J. Chuang, G. Ertl: Phys. Rev. Lett.57, 384 (1986)
F. Budde, A. Mödi, A.V. Hamza, P.M. Ferm, G. Ertl: Surf. Sci.192, 507 (1987)
J.W. Hepburn, F.J. Northrup, G.L. Ogram, J.C. Polanyi, J.M. Williams: Chem. Phys. Lett.85, 127 (1982)
B.D. Kay, T. Raymond: Chem. Phys. Lett.130, 79 (1986)
J.M. Bowman, J.L. Gossage: Chem. Phys. Lett.96, 481 (1983)
C.W. Muhlhausen, L.R. Williams, J.C. Tully: J. Chem. Phys.83, 2554 (1985)
J.C. Polanyi, R.J. Wolf: J. Chem. Phys.82, 1555 (1985)
J.W. Gadzuk, U. Landman, E.J. Kuster, C.L. Cleveland, R.N. Barnett: Phys. Rev. Lett.49, 426 (1982)
D.S. King, R.R. Cavanagh: J. Chem. Phys.76, 5634 (1982)
R.R. Cavanagh, D.S. King: InChemistry and Physics of Solid Surfaces, ed. by R. Vanselow, R. Howe, Springer Ser. Chem. Phys., Vol. 35 (Springer, Berlin, Heidelberg 1984) p. 141 ff.
J.L. Kinsey: J. Chem. Phys.66, 2560 (1977)
R. Schmiedl, R. Böttner, H. Zacharias, U. Meier, K.H. Welge: Opt. Commun.31, 329 (1979)
R. Schmiedl, H. Dugan, W. Meier, K.H. Welge: Z. Phys. A304, 137 (1982)
D.A. Mantell, R.R. Cavanagh, D.S. King: J. Chem. Phys.84, 5131 (1986)
E.E. Marinero, C.T. Rettner, R.N. Zare: Phys. Rev. Lett.48, 1323 (1982)
H. Rottke, K.H. Welge: Chem. Phys. Lett.99, 456 (1983)
G.D. Kubiak, G.O. Sitz, R.N. Zare: J. Chem. Phys.81, 6397 (1984); J. Chem. Phys.83, 2538 (1985)
H. Zacharias, R. David: Chem. Phys. Lett.115, 205 (1985)
L. Schröter, H. Zacharias, R. David: Appl. Phys. A41, 95 (1986)
L. Schröter, G. Ahlers, H. Zacharias, R. David: J. Electr. Spectr. Rel. Phen.45, 403 (1987)
L. Schröter, H. Zacharias, R. David: Surf. Sci. (in preparation)
A.S. Martensson, C. Nyberg, S. Anderson: Phys. Rev. Lett.57, 2045 (1986)
J.N. Russell, Jr., S.M. Gates, J.T. Yates, Jr.: J. Chem. Phys.85, 6792 (1986)
L. Schröter, H. Zacharias, R. David: In preparation
J. Müller: Phys. Rev. Lett.59, 2943 (1987) and private communication
R.I. Hall, I. Cadez, M. Landau, F. Pichou, C. Schermann: Phys. Rev. Lett.60, 337 (1988)
P.J. Eenshuistra, J.H.M. Bonnie, J. Los, H.J. Hopman: Phys. Rev. Lett.60, 341 (1988)
H. Rottke, K.H. Welge: J. Physique Cl46, 127 (1985) and to be published
M. Kori, B.L. Halpern: Chem. Phys. Lett.98, 32 (1983)
H. Rottke, H. Zacharias: Opt. Commun.55, 87 (1985)
S.L. Bernasek, S.L. Leone: Chem. Phys. Lett.84, 404 (1981)
D.A. Mantell, K. Kunimori, S.B. Ryali, G.L. Haller, J.B. Fenn: Surf. Sci.172, 281 (1986)
M. Kori, B.L. Halpern: Chem. Phys. Lett.110, 223 (1984)
C.A. Becker, J.P. Cowin, L. Wharton: J. Chem. Phys.67, 3394 (1977)
R.P. Thorman, D. Anderson, S.L. Bernasek: Phys. Rev. Lett.44, 743 (1980)
R.P. Thorman, S.L. Bernasek: J. Chem. Phys.74, 6498 (1981)
A.E. Bruno, U. Schubert, H.J. Neusser, E.W. Schlag: Chem. Phys. Lett.131, 31 (1986)
G.O. Sitz, A.C. Kummel, R.N. Zare: J. Vac. Sci. Techn. A5, 513 (1987)
M. Asscher, W.L. Guthrie, T.-H. Lin, G.A. Somorjai: J. Phys. Chem.88, 3233 (1984)
D.S.Y. Hsu, D.W. Squire, M.C. Lin: J. Chem. Phys. (to be published)
L.D. Talley, D.E. Tevault, M.C. Lin: Chem. Phys. Lett.66, 584 (1979)
G.S. Selwyn, M.C. Lin: Chem. Phys.67, 213 (1982)
G.S. Selwyn, G.T. Fujimoto, M.C. Lin: J. Phys. Chem.86, 760 (1982)
D.S.Y. Hsu, M.A. Hoffbauer, M.C. Lin: Surf. Sci.184, 25 (1987)
D.S.Y. Hsu, M.C. Lin: J. Chem. Phys.88, 432 (1988)
A. Rosen, S. Ljungström, T. Wahnström, B. Kasemo: J. Electr. Spec. Rel. Phen.39, 15 (1985); InLaser Spectroscopy VIII, ed. by W. Persson, S. Svanberg. Springer Ser. Opt. Sci., Vol. 55 (Springer, Berlin, Heidelberg 1987) p. 344ff.
A. Mödi, H. Robota, J. Segner, W. Vielhaber, M.C. Lin, G. Ertl: Surf. Sci.169, L341 (1986)
For a review see e. g. P. Piercy, Z.W. Gortel, H.J. Kreuzer: InAdvances in Multi-Photon Processes and Spectroscopy, Vol.3, ed. by S.H. Lin (World Scientific, Singapore 1987)
C.H. Mak, B.G. Koehler, J.L. Brand, S.M. George: J. Chem. Phys.87, 2340 (1987)
D. Burgess, Jr., D.A. Mantell, R.R. Cavanagh, D.S. King: J. Chem. Phys.85, 3123 (1986); and (in press)
J. Heidberg, K.-W. Stahmer, H. Stein, H. Weiss: J. Electr. Spectr. Rel. Phen.45, 87 (1987) and references therein
T.J. Chuang: Surf. Sci. Rep.3, 1 (1983); Surf. Sci.178, 763 (1986)
D.C. Jacobs, R.N. Zare: J. Chem. Phys.85, 5457 (1986)
D.C. Jacobs, R.J. Madix, R.N. Zare: J. Chem. Phys.85, 5469 (1986)
A.C. Luntz, A.W. Kleyn, D.J. Auerbach: Phys. Rev. B25, 4273 (1982)
G.C. Corey, M.H. Alexander: J. Chem. Phys.87, 4937 (1987)
D.C. Jacobs, K.W. Kolasinski, R.J. Madix, R.N. Zare: J. Chem. Phys.87, 5038 (1987)
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