Summary
New titanium(IV), vanadium(IV) and tin(IV) complexes with Schiff bases derived from 2-(2-aminophenyl)benzimidazole with benzaldehyde (L1) and salicylaldehyde (L2) have been prepared and have the general formulae MX4 · 2L (M = Ti, V or Sn; L = L1 or L2; X = Cl or Br).
All the complexes have been characterized by elemental analyses, magnetic measurements, e.p.r., electronic and i.r. spectral studies. The results show that the Schiff bases act as monodentate ligands. Tentative structures for the complexes are suggested.
Similar content being viewed by others
References
R. J. Sundberg and R. B. Martin,Chem. Rev., 74, 471 (1974) and refs. therein.
M. N. Hughes,The Inorganic Chemistry of Biological Processes, Wiley, London, 1972.
A. Mishra and J. P. Singh,J. Inorg. Nucl. Chem., 41, 905 (1979).
P. Souza, J. A. García-Vázquez and J. R. Masaguer,Transition Met. Chem., 9, 318 (1984).
P. Souza, J. A. García-Vázquez and J. R. Masaguer,Synth. React. Inorg. Met.-Org. Chem., 15, 247 (1985).
P. Souza, J. A. García-Vázquez and J. R. Masaguer,Transition Met. Chem., in press.
G. Brauer,Handbuch der Präparativen Anorganischen Chemie, Ferdinand Enke Verlag, Stuttgart, Vol. III, 1981.
Beilsteins Handbuch der Organischen Chemie, 25, 339.
A. Arquero, P. Souza, J. A. García-Vázquez and J. R. Masaguer,Transition Met. Chem., in press.
B. N. Figgis and J. Lewis in J. Lewis and R. G. Wilkins (Eds.),Modern Coordination Chemistry, Interscience, New York, 1968.
W. J. Geary,Coord. Chem. Rev., 7, 81 (1971).
F. Mani and G. Scapacci,Inorg. Chim. Acta, 16, 163 (1976).
J. Reedijk,Rec. Trav. Chim., 88, 1451 (1969).
J. B. Hodgson, G. C. Percy and D. A. Thornton,J. Mol. Struct., 66, 75 (1980).
M. Soares,Rev. Port. Quím., 6, 112 (1964).
N. S. Biradar and V. H. Kulkarni,J. Inorg. Nucl. Chem., 33, 2451 (1971).
H. H. Freedman,J. Am. Chem. Soc., 83, 2900 (1961).
J. E. Kovacic,Spectrochim. Acta, 23A, 183 (1967).
K. Kawakami, M. Miya-Uchi and T. Tanaka,J. Inorg. Nucl. Chem., 33, 3773 (1971).
L. Doretti, F. Madalosso, S. Sitran and S. Faleschini,Inorg. Nucl. Chem. Lett., 13, 607 (1977).
A. van der Vergen, R. J. Cozens and K. S. Murray,J. Chem. Soc. A, 3060 (1970).
J. I. Bullock and H. A. Tajmir-Riahi,J. Chem. Soc., Dalton Trans., 36 (1978) and refs. therein.
B. S. Saraswat, G. Srivastava and R. C. Mehrota,J. Org. Chem., 164, 153 (1979).
J. I. Bullock and H. A. Tajmir-Riahi,Inorg. Chim. Acta, 38, 141 (1980).
G. Condorelli, I. Fragalá, S. Giuffrida and A. Cassol,Z. anorg. allg.Chem., 412, 251 (1975).
L. Randaccio,J. Organometal. Chem., 55, C58 (1973).
J. I. Bullock, H. A. Tajmir-Riahi, M. F. C. Ladd and D. C. Povey,Acta Crystallogr., B35, 2013 (1978).
C. Sandorfy and S. Patai (Ed.),The Chemistry of the Carbon-Nitrogen Double Bond, Interscience, New York, 1970.
R. J. H. Clark,J. Am. Chem. Soc., 30, 1377 (1963).
J. E. Wertz and J. R. Bolton,Electron Spin Resonance, McGraw-Hill, N.Y., 1972.
I. Cuadrado and M. Morán,Transition Met. Chem., 6, 329 (1981).
M. Tiraut and T. D. Smith,Inorg. Chim. Acta, 90, 111 (1984).
W. E. Lindsell,J. Chem. Soc., Dalton Trans., 2548 (1975).
R. L. Carlin (Ed.),Transition Metal Chemistry, Vol. 3, Marcel Dekker Inc. N.Y., 1966.
P. F. Bramman, T. Lund and J. B. Raynor,J. Chem. Soc., Dalton Trans., 45 (1975).
B. R. McGarvey, in R. L. Carlin (Ed.),Transition Metal Chemistry, Vol. 3, Dekker, N.Y., 1966.
B. N. Figgis,Introduction to Ligand Fields, Interscience Publishers, N.Y., 1966, p. 277.
J. Dunn,Trans. Faraday Soc., 57, 1441 (1961).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Souza, P., García-Vázquez, J.A., Masaguer, J.R. et al. Complexes of titanium(IV), vanadium(IV) and tin(IV) with schiff bases derived from 2-(2-aminophenyl)benzimidazole. Transition Met Chem 11, 229–232 (1986). https://doi.org/10.1007/BF00619476
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00619476