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Study of interaction between ZrO2 (YSZ) substrates and YBa2Cu3O7−δ superconducting films

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The interactions between YBa2Cu3O7−δ superconducting films and ZrO2 substrates with different crystal orientations were investigated. Our results show that the crystal orientation of the substrate influences the orientations of the YBa2Cu3O7−δ crystals, whose c-axis have preferential orientations parallel to the surface of 〈100〉 ZrO2 substrates. The copper segregation in Y-Ba-Cu-O/〈ZrO2〉 films results from substrate reactions. Y, Ba, and Cu atoms diffusing into substrates were detected by AES and RBS techniques. A thin silver film evaporated on ZrO2 substrate as a buffer layer effectively slows down or eliminates the substrate interactions. The strong preferential c-axis orientation perpendicular to the substrate surface has been observed in the YBa2Cu3O7−δ /Ag/〈ZrO2〉 samples.

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This work has been supported by Science Foundation of Academia Sinica

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Chen, J.M., Zheng, Y., Chen, G.L. et al. Study of interaction between ZrO2 (YSZ) substrates and YBa2Cu3O7−δ superconducting films. Appl. Phys. A 48, 277–281 (1989). https://doi.org/10.1007/BF00619398

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  • DOI: https://doi.org/10.1007/BF00619398

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