Journal of Applied Electrochemistry

, Volume 3, Issue 3, pp 231–239 | Cite as

Carbon electrodes: Part 2. The anodic oxidation of N-propylamine

  • M. P. J. Brennan
  • O. R. Brown
Papers

Abstract

The anodic oxidation of a primary aliphatic amine, n-propylamine, has been studied at electrodes of vitreous carbon and pyrolytic graphite. The electrode reaction has been found to differ greatly for the two materials, as evidenced by the voltammetric behaviour at rotating disc electrodes and the results of preparative electrolyses. The observations at the vitreous carbon electrode are in agreement with the mechanism proposed by Mann and Barnes for the oxidation of propylamine at a stationary platinum electrode. A novel mechanism is proposed for the oxidation at a pyrolytic graphite anode.

Keywords

Oxidation Graphite Platinum Anodic Oxidation Platinum Electrode 

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References

  1. [1]
    M. Masui, H. Sayo and S. Tsuda,J. Chem. Soc. (B) (1968) 973.Google Scholar
  2. [2]
    N. A. Hampson, J. B. Lee, J. R. Morley and B. Scanlon,Can. J. Chem.,47 (1969) 3729.Google Scholar
  3. [3]
    N. A. Hampson, J. B. Lee and K. I. MacDonald,Electrochim. Acta,17 (1972) 921.Google Scholar
  4. [4]
    K. K. Barnes and C. K. Mann,J. Org. Chem.,32 (1967) 1474.Google Scholar
  5. [5]
    C. K. Mann,Anal. Chem.,36 (1964) 2424.Google Scholar
  6. [6]
    J. F. O'Donnell, J. T. Ayres and C. K. Mann,Anal. Chem.,37 (1965) 1161.Google Scholar
  7. [7]
    M. P. J. Brennan and O. R. Brown,J. Appl. Electrochem.,2 (1972) 43.Google Scholar
  8. [8]
    A. Bewick and O. R. Brown,J. Electroanalyt. Chem.,15 (1967) 129.Google Scholar
  9. [9]
    O. R. Brown,Electrochim. Acta,13 (1968) 317.Google Scholar
  10. [10]
    K. K. Barnes and C. K. Mann,Anal. Chem.,36 (1964) 2502.Google Scholar
  11. [11]
    J. F. O'Donnell and C. K. Mann,Anal. Chem.,36 (1964) 2097.Google Scholar
  12. [12]
    P. E. Malachesky, L. S. Marcoux and R. N. Adams,J. Phys. Chem.,70 (1966) 4068.Google Scholar
  13. [13]
    S. Karp,J. Phys. Chem.,72 (1968) 1082.Google Scholar
  14. [14]
    V. Yu. Filinovskii,Elektrokhimiya,5 (1969) 635.Google Scholar
  15. [15]
    M. P. J. Brennan and R. BrettleJ. Chem. Soc. PerkinI, (1973,) 257.Google Scholar

Copyright information

© Chapman and Hall Ltd. 1973

Authors and Affiliations

  • M. P. J. Brennan
    • 1
  • O. R. Brown
    • 1
  1. 1.Electrochemistry Research Laboratories, Department of Physical ChemistryThe UniversityNewcastle upon TyneUK

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