Transition Metal Chemistry

, Volume 10, Issue 10, pp 382–384 | Cite as

Cobalt(III), copper(II), and nickel(II) complexes of 1-thia-4,7-diazacyclononane-S-oxide

  • Matsuo Nonoyama
  • Kiyoko Nonoyama
Full Papers


The title complexes [ML2]n+=CoIII, CuII, NiII; L=1-thia-4,7-diazacyclononane-S-oxide) have been prepared and characterized spectroscopically. The sulphoxide group is coordinated through the oxygen atom and the complexes have atrans-O,O geometry. The nickel(II) complex of bis(2-amino-ethyl)sulphoxide has also been studied.


Oxygen Copper Physical Chemistry Nickel Cobalt 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. (1).
    Coordination Chemistry of Macrocyclic Compounds, G. A. Melson (Ed.), Plenum Press, New York, 1979.Google Scholar
  2. (2).
    M. Nonoyama and T. Ishida,Transition Met. Chem., 9, 367 (1984).Google Scholar
  3. (3).
    J. A. Davies,Advan. Inorg. Chem. Radiochem., 24, 115 (1981).Google Scholar
  4. (4).
    T. Kageyama,Y. Ueno and M. Okawara,Synthesis, 815 (1983).Google Scholar
  5. (5).
    A. B. P. Lever,Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968, Ch. 9.Google Scholar
  6. (6).
    L. J. Bellamy,The Infrared Spectra of Complex Molecules, 2, (Advances in Infrared Group Frequencies), 2nd. Edit., Chapman and Hall Ltd., London 1980, p. 195.Google Scholar
  7. (7).
    W. J. Geary,Coord. Chem. Rev., 7, 81 (1971).Google Scholar
  8. (8).
    Y. Yoshikawa and K. Yamasaki,Coord. Chem. Rev., 28, 205 (1979).Google Scholar

Copyright information

© VCH Verlagsgesellschaft mbH 1985

Authors and Affiliations

  • Matsuo Nonoyama
    • 1
  • Kiyoko Nonoyama
    • 2
  1. 1.Department of Chemistry, Faculty of ScienceNagoya UniversityNagoyaJapan
  2. 2.Konan Junior CollegeAichiJapan

Personalised recommendations